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Effect of Substituents on Acidity:
The complete effect of a substituent on acidity of substituted benzoic acids is because of two factors.
(i) Inductive effect: If the substituent uses-I effect, it increases the acidity of carboxylic acids, whereas if it exerts + I affect it decreases the acidity. Inductive effect affects all positions, i.e., o-, m- and p-.
limitation of Chrystal field theory
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