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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Osazone Formation - Test of Glucose Glucose on heating along with excess of phenyl hydrazine in acetic acid provides a yellow crystalline substance, m.pt. 205 ° C.
how we synthesis picric acid why it required 1 hour for the reaction with HNO3,H2SO4 and show the mechanism of picric acid and uses of picric acid. and what is the role of HNO3,H2S
(i) How would you account for the following: (a) The transition elements exhibit high enthalpies of atomization. (b) The 4d and 5d series of the transition metals have more
A 15 m 3 tank contains steam at 10 bar and 300 o C. The system is then cooled until the temperature reaches 150 o C . Some of the steam condenses. a) How much heat was transf
can you give me a sample problem of that topic and the answer step by step
what is the atomic weight of oxygen
n-propyl acetate evaporates rapidly when exposed to air,but water does not.Explain
why methane does not absorb IR radiation?
diversity of organic compounds
Q. What are Hexahalides? Hexahalides: S, Se-and Te react with excess of fluorine to give the corresponding hexafluorides. Fluorine being the most electronegative oxidises the
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