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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
4-nitrotolouene ---> LiAlH 4 converts it to 4-aminotoluene ----> Add HNO 2 and it forms -----> diazonium salt ------> add H 3 PO 2 to get Toluene -----> add Br 2 /CCl 4 - 2
why we use lithium in corey house reaction
given the mobility of hydrogen ion and cl to be 0.0000003623 and 0.0000000791 respectively. calculate the transference number of proton in the 0.001M solution of hydrocholric acid
What are uses of benzaldehyde
Give two methods for preparation of acetophenones
If n+l= 6 , then total possible number of subshells would be: (1) 3 (2) 4 (3) 2 (4) 5 Ans: 3
I have 11.2 L of a gas at stp. I need to use the molar volume to find how many molecules are in that gas.
give one book name about electromatric effect?&author name?
The number of electrons which can be accommodated in an orbital is: (1) One (2) Two (3) Three (4) Four Ans: Two
Matrix modifier method: GFAAS is a much more sensitive as compared to flame AAS and requires a very small sample size. More so, it does not require any sample preparation; eve
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