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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
the reaction equations for the dissociation of dithzone into chelate anions and the formation of metal-dithizone chelates
write 15 separation techniques with one diagram for each
while gibing the ph and the volume intial and final how do we calculate the number of moles
Starch and its derivatives Starch is a white amorphous substance along with no taste or smell. While heated to a temperature among 200-250 o C it changes into dextrin. At large
Q. What are the properties of water? Ans. Water is a colorless, odorless, tasteless liquid with a melting and freezing point of 0 o C and a boiling point of 100 o C at 1 a
240 g of water at 20 degree C are mixed with a sample of iron at 500 degree C. The final temperature of the system is 42 degree C. Find the mass of the iron sample
The configuration 1s 2 2s 2 2p 5 3s 1 shows: (1) Ground state of fluorine atom (2) Excited state of fluorine atom (3) Excited state of neon atom (4) Excited state
give a brief explaination of magnetic separation is. ?
Approximate the torque and power necessary to rotate the inner 20 cm diameter cylinder shown in Figure 1. SAE 10W-30 oil at 20°C fills the gap. Assume a linear velocity profile.
(a) Define the so-called 'colligative' properties, and write brief notes about each of them. (b) A system comprises two liquid components. State whether the system would be lik
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