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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Explain CMR spectrum 2,2-Dimethyl-1-propanamine (neopentylamine, (CH 3 ) 3 CCH 2 NH 2 ) has a maximum of three resonances in its CMR spectrum. 2-Methyl-2-butanamine, CH 3 CH 2
Reduction of Alkyne: Alkynes add on hydrogen in existence of appropriate catalysts like finely divided Ni, Pd. Determine if the triple bond is not found at the end of t
What are gredients for chemical and physical properties in lactic acid?
Antihistamines: Antihistamines are chemical substances that abolish/diminish the major actions of histamine released in the body and therefore avoid the allergic effects. Alter
I have the following reactions (1)NaOH+CO2+M=NaHCO3+M, K1 (2)NaHCO3+H=Na+H2CO3, K2 (3)2NaHCO3+M=(NaHCO3)2+M, K3 ki''s are the rate constants. Suppose NaHCO3 is a dominating constit
Energy of the electron in Hydrogen atom is given by: (1) E n = 131.38/ n 2 x kj mol -1 (2) E n = 131.33/n xkj mol -1 (3) E n = 1313.3/ n 2 x kj mol
Equivalent weight of salt how we can find
why ice flots on water
For ns orbital, the magnetic quantum number has value: (1) 2 (2) 4 (3) - 1 (4) 0 Ans:0
mention the condition required of maximum the yield of ammonia.?
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