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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
1. why YbS and YbI2 are semiconducting solids but LaS and LaI2 show metallic character. 2. Why is aqueous solution of Eu2+ thermodynamically less susceptible to oxidation than any
Homolysis bond fission or Homolytic (i) In homolysis bond, the covalent bond is broken in such a way that every resulting species gets its own electron. This is apt to the crea
Q. Quality of edible oils - fats? Various parameters are used for the assessment of the quality of fats and oils. Some of the important ones include determination of moisture c
i need help reading this IR chart to figure out what the compound is
Q. Test for the presence of argemone oil? This test helps to detect the presence of argemone oil. Argemone mexicana is the plant, which yields seeds of this oil. The seeds ar
The total post harvest system of cereal processing is given in the following flow chart:
unique properties of colloids
discovery of neutron becomes very late because
describe any three types of EDTA titrations.
Ernest Rutherford in 1909 conducted what is now a famous experiment where he bombarded gold foil with alpha particles (Helium nuclei). A source which undergoes for alpha decay is
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