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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Block diagram of atomic fluorescence spectrometry: The instrumentation for AFS consists of atom reservoir that might be a flame or a furnace etc., a basic source emitting the
Chemicals in food Several chemicals are added to food for their preservation and improving their appeal. These involve flavorings, antioxidants, fortifiers, sweeteners, dyes, e
You are given the following data taken in several runs in a mixed flow reactor: where - r A is the measured rate of disappearance of component A, and C A is the concen
The maximum number of electrons in p -orbital with n= s, m=1 is: (1) 6 (2) 2 (3) 14 (4) 10 Ans: 2
In a Bohr's model of atom when an electron jumps from n= 1 to n= 3 , how much energy will be emitted or absorbed: (1) 2.15 x10 -11 erg (2) 0.19
Define Recipe problem in experimental design method Recipe is one of the most important factors leading to successful food products. A recipe usually includes several ingredie
list of minerals with symbol
For the dissociation equilibrium of formic acid, HCO 2 H(aq) ↔ H + (aq) + HCO 2 - (aq), the acid dissociation constant at 298.15K has the value K a = 1.77 *10 -4 . (a) Find t
The number of unpaired electrons in carbon atom in excited state is: (1) One (2) Two (3) Three (4) Four Ans: Four
Ask Dear Sir Greetings Please be informed that I am an expert in Beekeeping at my Univ. We are intending to open new Dept. under the name under Honey Bee Dept. Consequently, we ne
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