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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Q. Illustrate the Quantum Mechanics? Ans: In 1924, a French scientist named Louis de Broglie proposed another model for the nature of the electrons in atoms. He predicted tha
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Explain the Electrode reactions and the cell reaction? A cell diagram, with its designation of the left and right electrodes, allows us to write reaction equations for the cell
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Q. How to change in Oxidation Number in Redox Reactions? Ans. In reduction-oxidation, or redox, reactions, atoms undergo changes in their oxidation numbers. Consider th
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Antipyretic: Antipyretic is a drug that is accountable for lowering the temperature of feverish object. The central nervous system, specifically the hypothalamus, takes an sig
Q. Example on Crystal field splitting in octahedral complexes? Here four ligands lie in one plane and the other two in a plane perpendicular to the first plane. Six ligands are
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