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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
how carbon tetra-valency lead to stability?
Why does calcium sulphate form scales in high pressure boilers
Q. Show Applications of coordination compounds? Innumerable applications of coordination compounds in fields as divergent as biology, industry. Agriculture, analytical chemist
hybridisation of o in boric acid
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Chemical Properties Proteins - Oxidation Oxidation : Proteins are oxidised on putrefaction and burning. The products comprise amines, nitrogen, carbon dioxide and water. The un
Q. Illustrate Classification of Emulsions? Emulsions are classified as: • Oil-in-water emulsion: This is a colloidal dispersion in which droplets of oil are dispersed in
Explain the following and give one example of each: a. Tranquillizers b. Mordant c. Hybrid rocket propellants
How does the composition of RNA vary from that of DNA, and how does that affect the chemical stability of the molecule?
The four quantum numbers of the valence electron of potassium are : (1) 4, 1, 0 and 1/2 (2) 4, 0, 1 and 1/2 (3) 4, 0, 0 and +1/2 (4) 4, 1, 1 and 1/
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