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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
difference between ion and free radicals ?
WHAT ARE THE APPLICATIONS OF LAW OF CHEMICAL COMBINATION
mechanism of make of hexane-1,6-dioic acid by Nitric acid
Measure the combustion energies for the burning of 1 mol of propane and butane gas in air under these conditions. Calculate the efficiency of the combustion process as a functi
If the velocity of hydrogen molecule is 5x 10 4 cm sec -1 then its de-Broglie wavelength is: (1) 2 Å (2) 4 Å (3) 8 Å (4)100 Å Ans: 4 Å
Physical properties of Adipic Acid (a) Adipic Acid is a white crystalline solid. Its melting point is 150°C. (b) Adipic Acid is fairly soluble in alcohol and ether but less
Why is the total energy of a many-electron atom not equivalent to the sum of the orbital energies for every electron?
curd formation in soya milk
The five d orbitals with distinct values of the magnetic quantum number (m) have the similar energy in a free atom or ion. In any compound they interact differently with the su
Containers in Illustrations C and D are identical Each container is 3.25'w x 3.25'w x 8.4'l Total capacity of each container 88.725 cubic feet Each container is filled wit
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