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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Draw the important resonance contributors for the benzenoium intermediate in the bromination of aniline and explain why ortho, para substitution predominates ?
Q. What do you mean by Emulsions? Emulsions, as you may already know by now, are colloidal dispersions of a liquid in another liquid with which it is immiscible. Emulsions can
interconversion of phenol to meta-bromo phenol
Q. Show the Multiple covalent bonds between electron pairs? Ans. Two atoms may share one electron pair, two electron pairs or three electron pairs. The bonds formed in th
Write the chemical equation for the entire combustion of heptane, C 7 H 16 . The heat of combustion for heptane is 4817 kJ/mol. How much heat could be released if 250 kg of hept
what are the applicatio of photochemistry
given the mobility of hydrogen ion and cl to be 0.0000003623 and 0.0000000791 respectively. calculate the transference number of proton in the 0.001M solution of hydrocholric acid
An electron has kinetic energy 2.8 x 10 -23 J . de-Broglie wavelength will be nearly: (me: 9.1 x 10 -31 kg) (1) 9.28x 10 -4 m (2) 9.28 x10 -7 m
The amount of energy released by burning a fuel source, measured in energy per mass, is called the fuel value. If all the energy obtained from burning 1.20 pounds of butane (fuel v
Why transition elements form interstitial compound
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