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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
This is an acid-catalyzed addition to the double bond much like hydration, except that an alcohol rather than water is the nucleophile that reacts with the carbocation intermediate
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Which of the following is always a whole number : (1) Atomic weight (2) Atomic radii (3) Equivalent weight (4) Atomic number Ans: Atomic number
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For the formation of covalent bond, the difference in the value of electron egativities should be: (1) Equal to or less than 1.7 (2) More than 1.7 (3) 1.7 or mor
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