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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Solid Nacl is a bad conductor of electricity since: (1) In solid Nacl there are no ions (2) Nacl Solid is covalent (3) In solid Nacl there is no motion of ions
Q. Describe Peroxomonosulphuric Acid? It is also known as permonosulphuric acid. It is obtained by the action of chlorosulphuric acid on cold anhydrous hydrogen peroxide :
Nitrogen atom has an atomic number of 7 and oxygen has an atomic number 8. The total number of electrons in a nitrate ion will be: (1) 8 (2) 16 (3) 32
A hydrocarbon z with molecular mass 78 on combustion gave 3.384g of carbon (IV) oxide and 0.693g of water. Determine the molecular formula of Z and draw its structure. [H=1, C=12,
diagonal relationship between boron and silicon
Methyl Lithium properties and uses
What is the instrumentation of aqueous titration.. What is the principle of aqueous titration and what is titration and it''s classification
lithium and beryllium markedly differ from others members of their respective group
A solution is prepared with 3.85g of a non-ionic unknown compound in 100.0g cyclohexane. The solution had a freezing point of 4.18 degrees Celsius. What is the molar mass of the un
For 1D particle in a box wave functions in a box of length L, evaluate a formula for the average energy in terms of the quantum number n: =?0L?*Hˆ?dx
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