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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Metallic Acetates - Acetic Acid For making several useful metallic acetates, illustrated as: (1) Basic copper acetate that is used for making green paints. (2) Al, Fe and
Classification of polymers - Elastomers The polymers which have elastic character such as rubber (a material that can return to its unique shape after stretching is said to be
Calculate the molar concentration of the solution essential to obtain the value of 10 molecules per µm2. (For this calculation we suppose that the transfer of the dye molecules fro
Explain and Define standard feat of formation Ans) The amount of heat liberated of absorbed when single mole of compound is formed in its standard state from its elements in the
Account for the soft nature of rubber material
The lengths of the C-C bonds in isobutene The lengths of the C-C bonds in isobutene have no significance; two are longer merely to accommodate the rest of the structure. Rememb
define it
Will benzylic halide undergo SN1 or SN2 mechanism ?Why? Ans) Benzyl chloride is a primary alkyl halide and undergo SN2 rapidly.
100 mol/hr pentane flows through an adiabatic heat exchanger where it is heated isobarically (at 2.5 bar) from 50°C to 250°C. The pentane is heated by contacting pipes filled with
Solvay process
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