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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
advantages and disadvantages of coulometer
The charge of an electron is -1.6 x10 -19 C. The value of free charge on Li + ion will be: (1) 3.6x 10 -19 c (2) 1x 10 -19 c (3) 1.6 x 10 -19
The compound in which cation is isoelectronic with anion is : (1) NaCl (2) CsF (3) NaI (4) K 2 S Ans: K 2 S
mechanism of bachmen reaction
Some of them show (S)-configuration at all their chiral centres. Illustrate their configurational formulae. If there is a meso-compound with this molecular formula illustrate it
Define the term - Local electric field and Polarization Local electric field: It's the sum of the electric field from external sources and field of the dipoles within the spe
Be 2+ is isoelectronic with: (1) Mg 2+ (2) Na + (3) Li + (4) H + Ans: Li +
Ratio scales It is also possible to record liking or acceptability using magnitude estimation scaling methods, but consumers may find it difficult to handle the concept of rat
structure of Bicyclo(3.3.1)non-1-ene
how to select a parent chain
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