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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Bakelite: It is thermosetting plastics which are most widely used and the most important plastics. Preparation: It is formed by condensation reaction of phenol an
A monosaccharide A has a molecular weight of 150 Da. The two stereoisomers B and C that are both optically inactive form when A reacts with NaBH4. Show all dissimilar stereoiso
Types of spectral interferences: While a quantitative analysis using a standard calibration curve is carried out, the calibration plot of emission intensity vs concentration o
what is the applications of condensation reaction
ramesh wants to coat the below silver articles with gold suggest the suitable coating process for ramesh to choose for coating the articles and justify the reason for the chosen me
give best example of ammalgam eletrod
The hybradization state of the Fe among [Fe(CN)6]3-,[Fe(CO)5] and [Fe(H2O)6]2+ is Ans) D2SP3,DSP3,SP3D2
The K sp of the phosphate fertilizer CaHPO 4 .2 H2O is 2.7 x 10 -7 at 25 o C. What is the molar concentration of a saturated solution? What mass of this compound will dissolve
Q.What do you mean by Electron Transfer and Ion Formation? Ans. Positive and negative ions do not form independently. The loss and gain of electrons means the electrons m
Cross linked polymers : 1. These are polymers where monomers unit are crosslinked together to make a three dimensional network polymers. 2. These kind of polymers are hard,
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