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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Bond enthalpies The most straightforward measure of the strength of a bond is the energy needed to break it. Estimates of such bond energies are usually obtained from thermo c
Q. Thermo d ynamics of Re d uction Process? As you have read above, metallurgy of most metals involves reduction of their oxides. The nature of the reduction process depends up
Polyfunctional Organic Compounds Organic elements that have two or more functional groups are known polyfunctional compounds. Their IUPAC names are acquired as follows, 1. P
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