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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
a) During coagulation, the colloidal particles stay un-aggregated because: b) The aim during water softening is to precipitate calcium and magnesium as calcium carbonate and mag
Types of spectral interferences: While a quantitative analysis using a standard calibration curve is carried out, the calibration plot of emission intensity vs concentration o
Interfacial Defects Grain boundaries are interfaces where crystals of dissimilar orientations meet. A grain boundary is a single-phase interface, with crystals on each n every
What volume of oxygen would be required to burn completely 200 ml of acetylene and what would be the volume of carbon dioxide formed?
Q. Illustrate Activity Series for Metals? Ans. An activity series is a series that orders substances on the basis of their reactivity. The following diagram is the activit
Q. Derive an expression for the standard molar reaction entropy of a reaction that can be used to calculate its value from the thermodynamic equilibrium constant and its temperatur
what is resonence effect on acidity
Reverse Hyperconjugation : The method of hyperconjugation is as well observed in the system given below, In such type of system the effect operates in the opposite direc
eperiment on conductometric titration on acids and bases
what are the diferent types of indicators and describe them
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