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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Q. Show the solubility of double salts? The solubility of double salts of lanthanides such as 2Ln (N0 3 ).3Mg (N0 3 ) 2 .24H 2 0 and Ln2 (S0 4 ) 3 . Na 2 S0 4 .xH 2 0 increase
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Properties of Nitrophenols: O-Nitrophenol is a yellow in colour crystalline compound, whereas m- and p-isomers are colourless crystalline compounds. Isomer orth
The electronic configuration of an element is 1s 2 , 2s 2 2p 6 3s 2 3p 6 3d 5 4s 1 . This represents its: (1) Excited state (2) Ground state (3)Cationic for
Carbohydrates The carbohydrates are naturally taking place organic molecules. They exist in both of the animals and plants. "Carbohydrates are ddescribed as a class of comp
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Highest covalent character is found in: (a1 CaF 2 (2) CaCl 2 (3) CaBr 2 (4)
Disaccharides - Biomolecules The disaccharides give in on hydrolysis two monosaccharides. Those disaccharides that generates two hexoses on hydrolysis contain a general formul
Askccomparison between caulometry and electrogravimetry question #Minimum 100 words accepted#
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