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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
In the Lectures where the necessary heat transfer area for the production of aspirin was being discussed, we had calculated (a) the volume of the scaled up version of the tank and
Scale and sludge formation in boiler
Write a feature which will distinguish a metallic solid from an ionic solid. a) Explain 'order of a reaction'. b) What is an emulsion?
what do you mean by homologous series .
The two or more chemical compounds with identical chemical formula but different structures are called isomers, and the phenomenon is known as isomerism. This phenomenon is not res
Q. What do you know about Chemical Equilibrium Many chemical changes are reversible and will proceed towards an equilibrium instead of going to completion. The products react w
#ques(a) Given the values below, calculate the concentration of benzoyl peroxide required to prepare polystyrene with a number average molar mass of 400,000 by bulk free radical po
The five d orbitals with distinct values of the magnetic quantum number (m) have the similar energy in a free atom or ion. In any compound they interact differently with the su
Interconversion of the resonance structures of carbon monoxide with the curved-arrow notation: Because the carbon in the structure on the left has a sextet of electrons, it
The valence electron in the carbon atom are: (1) 0 (2) 2 (3) 4 (4) 6 Ans: 4
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