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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
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Q. Classification of emulsifiers? Emulsifiers can be classified under two categories. These are: • Natural: These are naturally present in foods. Some examples are phosphol
The wavelength of a spectral line for an electronic transition is inversely related to: (1) The number of electrons undergoing the transition (2) The nuclear charge of the a
1. Consider a platinum crystal structure (FCC, R Pt = .139 nm). a. Sketch the (100), (110), and (111) planes (including the atoms in the second layer if they can be observed
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Explain heat of Combustion? Ans) The amount of heat liberated when single mole of any substance is completely burnt in oxygen is known as heat of combustion H is negative for he
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Price ceiling problems: The persistent shortage created by price ceiling will in turn pose the following problems: Rationing Government may have to apportion the quantity s
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