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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
chemistry of f block elements
How are the following conversions carried out? (i) Benzyl chloride to benzyl alcohol, (ii) Methyl magnesium bromide to 2- methlpropan -2-ol,
assignments of hydrogen bonding
50ml of 0.1M NH 4 OH ,25ml NH 4 Cl weere used to make a buffer . what is the PH is if Pk b is 4.8? Solution) The given buffer is a base buffer [NH4OH] =[(50*0.1)/75] [NH4Cl] =[(
Properties of Catechol 1. Catechol is a colourless crystalline solid, its melting points is 105°C. 2. Catechol is soluble in water. 3. Catechol is exaggerated on exposure
What is a salt bridge? Salt bridge is a device used to link two electrodes on electrochemical cell. It maintains electrical neutrality and internal continuity. It is shown by
reactivity of f-block elements
A heat recovery device involves transferring energy from hot flue gases passing counter currently through an annular region to pressurized water flowing through the inner tube of t
zinc+copper(ll) chloride
The number of nodal planes in a Px is: (1) One (2) Two (3) Three (4) Zero Ans: One
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