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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
WHAT ARE SOLUBILITY?
how was the magnitude of electric charge concluded?
Metallic Acetates - Acetic Acid For making several useful metallic acetates, illustrated as: (1) Basic copper acetate that is used for making green paints. (2) Al, Fe and
in castner kelnar process sodium metal extract at cathode and calcium also why they do not mix if they extract at same chamber?
The quantum number 'm' of a free gaseous atom is associated with : (1) The effective volume of the orbital (2) The shape of the orbital (3) The spatial orientation of the
For the dissociation equilibrium of formic acid, HCO 2 H(aq) ↔ H + (aq) + HCO 2 - (aq), the acid dissociation constant at 298.15K has the value K a = 1.77 *10 -4 . (a) Find t
Discuss hartree-fock self consistent field theory . what are its demerit.
various concepts of acid and base
Physical properties of Amino acids (a) Amino acids are colourless, crystalline substances comprising sweet taste. They melt along with decomposition at higher temperature (much
ENTHALPY
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