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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
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Verify the transfer function C(s)/R(s) for the block diagram given below.
Q. Explain Colligative properties of Solutions? Colligative properties of solutions are those properties which depend on the concentration of the solution rather that the ty
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How many electrons can be accommodated in a sub-shell for which n=3, l=1: (1) 8 (2) 6 (3) 18 (4) 32 Ans: 6
What are non-ideal solutions? Define as to why non-ideal solutions deviate from Raoult's law.
Nuclei contain uncharged neutrons and positively charged protons; these two particles with about the same mass are known as nucleons. The number of protons is the atomic number of
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What parts of molecular forces are expected to exist between the species in any three of the following pairs constituting mixtures? (a) He and N2 (b) Cl2 and NO- 3 (c) NH
Q. What are the properties of liquids? Ans. Evaporation of Liquids When we place a liquid in an open container, it slowly disappears. If we heat a liquid it disappear
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