Define ionisation isomerism, Chemistry

Assignment Help:

Q. Define Ionisation Isomerism?

Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04  which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red  isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in  solution. Other examples are:

[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI

[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.


Related Discussions:- Define ionisation isomerism

Estimation of ferric ion, In ion estimation why we have to change the oxida...

In ion estimation why we have to change the oxidation state of the Fe+3 ion. Ans) Because if iron is in +3 oxidation state it will be morestable then we get preferable product. s

Entropy and free energy, Entropy (S) is a molecular 'disorder', or more pre...

Entropy (S) is a molecular 'disorder', or more precisely 'the number of microscopic arrangements of energy possible in a macroscopic sample'. Entropy depends strongly on the state

Classification of polymers - natural polymer, Classification of polymers - ...

Classification of polymers - Natural polymer The polymers acquired from nature (plants and animals) are known as natural polymers. These types of polymers are extremely essenti

Explain cesium fluoride, Explain cesium fluoride Compound (2), cesium f...

Explain cesium fluoride Compound (2), cesium fluoride, would be most likely to exist as an ionic species, due to Cs and F come from opposite corners of the periodic table.

Calculate the evaporator pressure and rate of heat, A liquid stream contain...

A liquid stream containing half n-hexane and half n-pentane at 80°C and 5 atm is fed at a rate of 100 mol/hr to a flash evaporator operating at pressure (P) and 65°C. The decrease

Transition elements, Why transition elements form interstitial compound

Why transition elements form interstitial compound

MOHRS SALT, write the prepation of mohrs salt..

write the prepation of mohrs salt..

Illustrate the given observations, Illustrate the following observations: ...

Illustrate the following observations:  (a) Cottrell's smoke precipitator is fitted at the mouth of the chimney used in factories.  (b) Ferric hydroxide sol. Gets coagulated

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd