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Clausius inequality - thermodynamics:
Whenever closed system undergoes cyclic process, cyclic integralis less than zero (that is negative) for an irreversible cyclic process and equal to zero for a reversible cyclic process.
The efficiency of reversible H.E. operating within temperature T1 & T2 can be given by:
or for a reversible engine. .......(i)
Now efficiency of irreversible H.E. operating within same temperature limit T1 and T2 can be given by
Combining equation (i) and (ii); we get d ≤ 0 The equation for irreversible cyclic process can be written as: + 1 = 0 I = Amount of irreversibility of cyclic process.
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Q= In an investigation of the thermodynamic properties of alpha-manganese,the following heat contents determined H 700 - H 298 = 2895 cal/g-atm H 1000 - H 298 = 5450 cal
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Application of group technology point wise
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