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Chemiluminescence Lab Questions
Intent of lab: To synthesize 1,2-dioxetanedione which reacts with a polyaromatic molecule to produce light. 0.37g sodium percarbonate (containing 0.0035 mol H2O2) is added to test tube with 1mL of prepared (COCl)2 solution in it. (Note: in 10mL of prepared (COCl)2 solution there is 0.4mL (COCl)2 in 9.6mL CH2Cl2). 5 test tubes are used in this experiment overall.
1. What one reagent should "re-energize" the light solution after it has faded? Explain using moles and limiting reagents.
2. Draw the mechanistic arrows showing how 1,2-dioxetanedione breaks down to 2 CO2 molecules.
Determine how much energy will be required to heat 69.7 gal of H 2 O from 22 degree Celsius to 110 degree Celsius if it is given that 1.00 gal weighs 3.77 kg and water has a specific heat capacity =4.184 J/g C
Determine the hydraulic conductivity and transmissivity of the aquifer and What would Q be if the hydraulic gradient
Calculating concentration of an ion, Given the concentration of hydroxide ions, use the ion product constant of water to calculate the concentration of the other ion at 298 K
Determine the numbers of moles of iron that would be formed from 6.2 moles of CO (carbon monoxide) combining with excess of iron (III) oxide (Fe2O 3 )?
In the bromination of ethane (C2H6) reaction, one wants to produce 10.0 g of C2H5Br product. How many grams of C2H6 would be needed to react with excess Br2.
Calculating Value of Kb in Substances and pKb for Base, Codeine (C18H15NO3) is a weak organic base. A 5.0x10-3 solution of codeine has a pH of 9.95.
determine at what pressure will pure H 2 O start to boil if its temperature is seventy five degree Celsius
A buffer is made up 0.24 M propanoic acid, CH3CH2COOH, a weak monoprotic acid, and 0.17 M of sodium propanoate, CH3CH2COONa. What is the pH of the solution.
Suppose that 0.82 g of water condenses on a 80.0 g block of iron that is initially at 24 C.If the heat released during condensation goes only to warming the iron block
What molar ratio of sodium acetate to acetic acid should be used to prepare a buffer with pH = 4.5? Ka acetic acid = 1.8 x 10-5.
osmium has a density of 22.6 g/cm3. what volume (in mL) would be occupied by a 21.8 g sample of osmium?
Both potassium chloride (KCL) and potassium hydroxide (KOH) are very soluble in water. However, as one increases the temperature of the solution, KCL becomes more soluble and KOH becomes less soluble. Explain
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