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Important information about Conceptual Organic chemistry
1) What chemical tests might be used to distinguish between pentanal and 2- pentanone; between benzyl alcohol and diphenylmethanol?
2) The haloform reaction using 12 and NaOH is referred to as the "iodoform" test for methyl ketones. The test also gives positive results for compounds containing the -CH(OH)CH3 group. This results from the oxidation of the alcohol to the methyl ketone in the first stage. Write a balanced equation for the conversion of C6H5CHOHCH3 to the methyl ketone in the presence of 12 and NaOH. Identify which species is being oxidized and which is being reduced.
3) If you were carrying out an industrial scale synthesis in which one step involved a haloform reaction to convert a methyl ketone into the corresponding acid having one less carbon atom, would you use NaOH and C12, NaOH and Br2, or NaOH and 12 reagent? Give reasons for your choice.
4) Over the years the two isomers of azobenzene have been designated by various terms: cis-trans, syn-anti, and E-Z. Using each set of terms, assign them to the isomers of azobenzene.
You are given trhat 0.01 m aqueous solutions of each of the given solution as, C6H12O6, K3PO4, CaCl2 , NaI you jutst need to place the given solutions in order of increasing change in the freezing point of the solution.
If the temperature of the water in your reaction bowl is 23 C, what is the temperature of the hydrogen gas.
a sample of gaseous SiH4 weighing 0.425g is placed in a 580 mL container. The resulting pressure is 0.61 atm.What is the temperature in degree celsius.
Determine what is the coordination of the cations in the case of a normal spinel and what point defects are possible in the spinel structure?
What happened when 6.0M HCl was added to the contents of the tube in 7a above?
Suppose that 160 g of ethanol at 30?C is mixed with 230 g of ethanol at 76?C at constant atmospheric pressure in a thermally insulated vessel.
how many grams of vinegar are required to react completely with 25.0g of baking soda.
iF 0.80g of a gas occupies 295 mL at 25 degrees Celcius and 680 mm Hg of pressure, what is the molar mass of the gas.
Explanation for the Chemical Structure of Hydrocortisone, Can you please explain the chemical structure of cortisol and hydrocortisone? What is the difference on the structure? How many functional groups hydrocortisone has and what are they?
Using the following reaction: OH- + HC2H3O2 ---> H2O + C2H3O2- a 75.0 mL sample of potassium hydroxide, KOH, of unknown concentration is titrated with 42.5 mL of 0.575 M acetic acid.
Compute ΔU for the transformation; a = 0.136 m6Pa mol-2 ; b = 0.0391 L/mol.
what volume and mass of steam at 100c and 1.00 atm would release the same amount of energy during condensation as 100.cm3
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