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1) Heroin is 3, 6-diacetylmorphine. Heroin is 2-3 times more potent than morphine.
In vitro and in vivo, to which product does heroin hydrolyze first, (3- or 6-acetylmorphine), and why?
Hint: What are the acidic pKa values of the respective hydroxyl products? Look up the structures on the internet or use the UF library online e-journals.
2) Acetylsulfisoxazole, is readily hydrolyzed in vivo to sulfisoxazole. On the other hand, the acyl group in amikacin, is stable to hydrolysis in vivo. Both N-acetylsulfisoxazole and N-acetylamikacin are acyl derivatives where the acyl group is attached to nitrogen.
Why is one stable and the other not?
Hint: What are the acidic pKa values of the respective N-H groups formed on hydrolysis. Look up the structures on the internet or use the UF library online e-journals.
the mass loss of the iron nail was 1.511. How many moles of iron were converted to Fe3+?
Determine the linear and volume shrinkages that occur during the drying and sintering of a gel containing 5 vol% solids if the dried gel and the sintered gel have a solids content (relative density) of 50% and 100%, respectively
If the sign for delta G is negative (spontaneous process) and the sign for delta S is positive (more disorder) for both dissolving processes, how could one be endothermic (positive delta H) and one be exothermic
a 20.0-milliliter sample of .200-molar k2co3 solution is added to 30.0 milliliters of .400-molar bano32 solution.
Explain a water sample is found to contain the pollutant chlorofluorobenzene CFB with a concentration of 25 ppb (by mass). Explain what volume of this water contains 7.50E2 mg of CFB presume a density of 1.00 g/mL)
Poly(propylene) is made of one kind of monomer. Give the two monomers used to make nylon 6,6. Why are two monomers needed to make nylon 6,6 while only one is needed to make poly(propylene)?
q1. given that the internal energy of water at 55 bar pressure is 1178 kj kg-1 and that the specific volume of water at
The excess I2(aq) left over from the above reaction was titrated with 11.37 mL of 0.0105 M thiosulfate (S2O32-) as follows: I2(aq) + 2S2O32-(aq) → 2I1-(aq) + S4O62-(aq)
What is the difference between a dipole-dipole interaction (permanent) and an induced dipole interaction (temporary). Examples please.
Problem- Calculate the pH of the following solutions: a solution that is 9.5 x 10^-2 M in potassium propionate KC3H5O2 and 7.0 x 10^-2 M in propionic acid HC3H5O2. Ka of propionic acid is 1.3 x 10-5
Carbon monoxide competes with oxygen for binding sites on the transport protien hemoglobin. CO can be poisonous if inhaled in large quantities. A safe level of CO in air is 50 ppm
the effect of temperature on gases confined to small volumes. What is the pressure of 3.40mol of gas D measured at 251 C in a 1.75-L container assuming real behavior?
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