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Use a systematic treatment of equilibrium to calculate the pH of a solution prepared by diluting 0.467 g of aniline (aminobenzene, C6H5NH2) to 100.0 mL. Pertinent equilibria include the dissociation of the weak base and the autoprotolysis of water. a. Write out the mass balance and charge balance equations. b. Write the associated equations for the equilibrium constants for the pertinent equilibria. c. Make the assumption that [BH+] ~[OH-] and solve for [OH-]. Calculate the pH of the solution. Verify that the assumption was justified. Calculate the fraction of dissociation a.
For the equilibrium H2+CO2-> Kc= 3.18 at 1106K. If each of the 4 species was initially present at a concentration of 3.000M.
A 122 piece of metal is heated to 285 and dropped into 84.0 of water at 26. If the final temperature of the water and metal is 58.3, what is the specific heat of the metal.
A 24.9 mL volume of HCl reacts completely with 55.0 mL of aqueous Na2CO3. The reaction is as follows: 2HCl (aq)+ Na2CO3(aq) ->CO2(g)+H2O(l)+2NaCl(aq) The volume of CO2 formed is 141 mL at 27°C and 742 mmHg.
When 5.6 grams of NaCl are dissolved in enough water to create a 125-gram solution, what is the solution's concentration, expressed as a percent by mass?
The rate constant for a certain reaction is k = 2.60×10-3 s-1 . If the initial reactant concentration was 0.200M , what will the concentration be after 14.0 minutes?
A lead bullet is fired at a wooden plank. At what speed must bullet travel to melt on impact, if its initial temperature is 25oC and the heating of the plank is neglected.
What mass of potassium bromide residue remains if 500.0 mL of 0.200 M potassium bromide solution are evaporated to dryness?
How many moles of carbon, hydrogen, & oxygen are present in a 100g sample of ascorbic acid? Ascorbic acid (vitamin C) contains 40.92% carbon, 4.58% hydrogen, and 54.50% oxygen by mass. Assume a 100 g sample of ascorbic acid.
Ideally what should the ratio between the three slopes (AlCl3 slope= 483.0 , CaCl2 slope= 421.4, and NaCl slope= 181.9) be? What are your actual experimental ratios?
If the O2 gas present in 7.30 L at STP is changed to a temperature of 17 degrees Celsius and a pressure of 788 Torr, what will be the new volume?
Determine what is the final volume the gas occupies If the pressure of a gas inside the cylinder changes from 840.0 mmHg to 360.0 mmHg,?
If 4.00 g of the unknown compound contained 0.133 mol of and 0.267 mol of H , how many moles of oxygen, O , were in the sample?
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