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(a) If the total concentration of acetic acid ([CH3COOH] + [CH3COO- ]) in a river is 3 x 10-3 moles per liter and the pH of the river water is 4.8, what is the concentration of negative charge due to the acetate ions? [The pKa value of acetic acid is 4.8.]
The answer is 1.5*10^-3 moles (-)/L
(b) Propionic acid is CH3CH2COOH, and its pKa is 4.9. If propionic acid occurs in a river and the pH of the river water is 8, what is the ratio of (CH3CH2COO - ) to (CH3CH2COOH) in the water?
(c) Assume that the total concentration of propionic acid in a river is 1 x 10-3 moles per liter and the total concentration of acetic acid is 3 x 10-3 moles per liter. If these two acids were the only organic compounds in the river, what would be the concentration of dissolved organic C in the water (in mg L-1 )?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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