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Treatment of (S)-( )-5-methyl-2-cyclohexenone with lithium dimethylcuprate gives, after protonolysis, a good yield of a mixture containing mostly a dextrorotatory ketone A and a trace of an optically inactive isomer B. Treatment of A with zinc amalgam and HCl affords an optically active, dextrorotatory hydrocarbon C. Identify compounds A, B, and C, including stereochemical configurations. Be sure to explicitly draw H and both wedge/dash bonds at any configuration center.
What is the equilibrium concentration of Cl at 1000 ? What is the equilibrium concentration of COCl2 at 1000 ?
Iron can be prepared by the reaction of Fe2O3 with carbon according to the equation: 2Fe2O3(s) + 3C(s) 3CO2(g) + 4Fe(s) If 401 g Fe2O3 and 205 g C are heated together, how many grams of iron could be produced?
Balancing equation to calculate correct number of moles If CaC2 + 2 H2O --> C2H2 + Ca(OH)2 then, there are 65 grams of calcium carbide
When 27.5 mL of 0.520 M H2SO4 is added to 27.5 mL of 1.04 M KOH in a coffee-cup calorimeter at 23.50°C, the temperature rises to 30.17°C. Calculate
An equilibrium mixture at 225 degrees C contains 0.10 M NH3 and 0.20 M H2 for the reaction 3H2 (g) + N2 (g) --- 2NH3(g) If the Kc at this temperature is 1.7 X 10 2.
Important information about Identifying unknown substances, Compound A (C7H14O) burned with a yellow, nonsooty flame and did not decolorize a bromine-methylene chloride solution. It did give a positive 2,4-dinitrophenylhydrazine test
The zinc content of a 1.23 g ore sample was determined by dissolving the ore in HCl, which reacts with the zinc, and then neutralizing excess HCl with NaOH. Zn+2HCl-->ZnCl2+H2
What mass of sodium hydrogen carbonate is needed to make the buffer solution 0.10 M in sodium hydrogen carbonate? pH is 10.1 pka is 10.33.
The heat of fusion of water is 335 J/g. How much heat would be required to melt 47.5 g of ice?
Write a balanced net ionic equation for the reaction of KMnO4 with the saturated solution of CdC2O4 in diluted H2SO4. The major products are Mn2+ and CO1
Calculate the molar solubility of AgBr in a 1.00 M aqueous solution of ammonia. Then calculate the solubility of AgBr in pure water, and compare the two solubilities. (Ksp for silver bromide is 7.7x10 -13 and Kf for Ag(NH3)2+ is 1.6x10^7)
A 4.50-g sample of LiCl at 25.0 C dissolves in 25.0 mL of water also at 25 C. The final equilibrium temperature of the resulting solution is 60.8 C.
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