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A mass of G grams of a liquid are placed in a closed 15 liter, fixed-wall container. The molecular weight of the liquid is 18 g mol-1. Its molar heat of vaporization is 44 kJ mol-1. Its normal boiling point is 373 K. A scientist measures the pressure inside the container as a function of temperature and notes that for temperatures at or below 512 K, the pressure increases exponentially with T-1. However, for the temperatures above 512 K, the pressure is found to increase linearly with temperature. (Assume the heat of vaporization is independent of temperature.)
(a) determine the original mass of liquid, G, that was placed in the container. (Ignore the volume occupied by the liquid in these calculations)
(b) Determine the pressure that will exist inside the container when T= 512 K.
2-Methylpentane and 4-methyl-2-pentanone are constitutional isomers with the molecular formula C6H12O.each shows a molecular ion peak in its mass spectrum at m/z 100.
Dry ice (solid CO2 ) has occasionally been used as an "explosive" in mining. A hole is drilled, dry ice and a small amount of gunpowder are placed in the hole, a fuse is added, and the hole is plugged.
A voltaic cell consists of a Zn/Zn2+ half-cell and a Ni/Ni2+ half-cell at 25 ?C. The initial concentrations of Ni2+ and Zn2+ are 1.50M and 0.100M , respectively. The volume of half-cells is the same.
If you a litre (1000mL) bottle of oil in your engine, how much heat is produced in kcal?In BTU To solve this problem you must know the density of motor oil is .82 g/mL.
Assuming the various solutions are used without dilution with water,how would you prepare 50ml of a buffered medium to keep pH essentially constant at 5.40 in an enzyme experimement in which acid will be produced?
Two of the following ions depend on their conversion into a gas for detection. What are the 2 ions? The two ions will form an ionic compound.
Carbonic acid is an intermediate step in the transport of CO2out of body. If the pH of blood is 7.4, what percent is carbonic
One of the advantages offered by a synthetic detergent is that it won't form "soap scum" with hard water. Show the chemical reaction that a soap (use RCO2-) undergoes with calcium or magnesium ions
consider the reaction CO2+H2=CO+H2O.The equilibrium concentrations are [CO]= 0.050M, [H2]=0.045M, [CO2]=0.086M, and [H2O]= 0.040M. Calculate K .
Determine how many moles of gas were added to the container If the pressure raised to 800. torr,?
Which of the five cobalt complexes, [Co(NH3)5X]^y+ (where X is one of the five ligands, Br-, Cl-, F-, H2O, or NH3 and y is the magnitude of the positive charge) will absorb the shortest wavelength of light? Which will absorb the longest wavelength..
What is the pressure of the gas in mmHg if the volume is changed to 8.53 L? The temperature remains constant. In scientific notation.
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