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Rank the substrate structures below according to rate of reaction with 1% ethanolic silver nitrate (SN1) (1 is the fastest to react and 6 is the slowest to react). If two or more compounds appear to react at the same rate, then assign them the same number (ie you may have two #1's, etc). Next, rank the substrate structures below according to rate of reaction with sodium iodide in acetone(SN2).
Primary alky halide
Secondary alky halide
Tertiary alky halide
Allylic Primary alky halide
Benzylic Primary alky halide
sp2 alky halide
Find the standard free energy change in G at 25 C for the following reaction using standard free energies of formation. What is the value of K at 25 C for this process?
Consider a reaction of the type aA--->products in which the rate law is found to be rate=k(A)3 If the first half of the reaction is found to be 40 seconds what is the time for the second half life
The standard enthalpy change for the reaction below is -905.4 kJ (for the reaction as written). What is the standard enthalpy of formation of NO(g)
the rotational temperature θR=0.0538 k and the vibrational temperature θv = 308.65 K. would the vibrational contributions to U-U(0) and Cv still be significant at 100K? please explain.
When electrical current of unknown magnitude is run through the device for 3.50 min, 16.1 mL of water-saturated H_2(g) is collected. The temperature and pressure of the system are 25 degreesCelsius and 715 torr.
A section of membrane with an aquaporin (AQP) has a water transport rate of about 3 billion water molecules per second (3 × 109 molecules·s-1).
Show the Newman projection of chair-cyclohexane. From this structure, why is this the lowest energy-conformation
how to calculate the concentration of a standard solution and the concentration of KMnO4 the mass of sodium oxalate used was 0.8367g and then it was diluted down with 50ml water, and 20ml H2SO4 then 25 ml of that solution
69.7 grams of solute with a molecular mass of 2790 grams are dissolved in enough water to make 1.00 dm3 of solution at
For the saturated fatty acid palmitate, how many QH2, NADH, and acetyl-CoA molecules can be generated by complete ?-oxidation? How many total ATP can be produced from palmitate? If a single cis-double bond is added, how many total ATP can be made?
Draw the major organic product from the reaction of 2-(carboxymethyl)benzoic acid with acetic
At a certain temperature, the root mean square speed of CH4 molecules is 1610 km/h. what is the root mean square speed of CO2 molecules at the same temperature ?
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