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1. You are studying a reaction wherein compound X is dehydrogenated to yield compound Y, and in the absence of a catalyst you have determined that the ?Go under standard conditions of pH 7 and 37o (RT = 0.59 kcal/mole) has a value of +0.7 kcal/mole.
A. (4 pts) If you start with 100,000 molecules of X, how much, if any, Y will be generated when you reach equilibrium? Explain your answer.
B. (6 pts) You have isolated an enzyme that catalyzes this reaction by coupling it to the hydrolysis of a high energy intermediate. At equilibrium, only 650 molecules of X remain from the initial 100,000 molecules. Given the following table of ?Go for the hydrolysis of three phosphate-containing compounds, which of these three compounds is the least wasteful energy source for the coupled reaction?
Reaction
Hydrolysis of phosphoenolpyruvate has a deltaGo of -14.8 kcal/molHydrolysis of ATP to ADP + Pi has a deltaGo of -7.3 kcal/molHydrolysis of glucose 6-phosphate has a deltaGo of -3.3 kcal/mol
Calculate the heat capacity of methanol (methyl alcohol) at 40°C. 2.6kg of methanol at 15 C enter an evaporator. They exit as vapour at the boiling point.
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Standardization of Na2S2O3, Added 0.12 g KIO3 and dissolved in 75 mL of distilled water. Added .20 g of KI to solution, then added 10 mL of 1M HCl and immediately titrated with thiosulfate solution (made by weighed 25 g of Na2S2O3-5H20
Hypervenilation raises the pH of the blood in a condition known as respiratory alkalosis. Common treatment is to have the patient breathe into a paper bag,
A compound has the empirical formula CH2O. When 0.0866 g is dissolved in 1.000 g of ether, the solution's boiling point is 36.5°C. Determine the molecular formula of this substance.
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