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The mass spec of a yellow, diamagnetic solid A, a neutral metal carbonyl, reveals a molecular ion peak of 390 amu. A fragmentation pattern consisting of sequential losses of 28 amu (CO) occured until m/z = 110 amu. Consider the following conditions: -Treatment of A with Cl2 affords 2 mols of white crystalline solid B whose IR spectrum is similar to A - Treatment of A with Na(Hg) in THF affords 2 mols of air-sensitive salt C. - Reaction of C with H3PO4 gives colorless D. NMR of D exhibits resonance at -4 ppm. - On heating D, a flammable gas and A are formed. - Reaction of C with CH3I affords white solid E whose proton NMR shows a single resonance around 0.2 ppm. Identify A-E.
From the data below, calculate the total heat (in Joules) needed to convert 0.333 mol of gaseous Ethanol (MW - 46.07 g/mol) at 300 degrees Celsius
A particular snack mix contains 1.30 g of salt per 100 g of the mix. How much mass of the mix can be consumed and still be within the FDA limit of 2.40 g of salt.
What is the energy of a C-C bond in kJ/mole? Explain. How does this amount of energy compare?
Balance the following equation in basic solution. indicate which reactant becomes oxidized during the reaction, which reactant becomes reduced
A 19.0 kg piece of zinc at 67 degrees Celsius is placed in a container of water. The water has a mass of 23 kg and has a temperature of 9.4 degrees Celsius before the zinc is added. What is the final temperature of the water and zinc?
a solution of 100 ml of .200 M KOH is mixed with a solution of 200 ml of .150 M NiSO4. what is the chemical equation, what precipitate forms, what is the limiting reagent, and how many grams of the precipitate form?
CH4 + 2 O2-> CO2 + 2 H2O How many grams of CO2 are formed from the combustion of 9.00 moles of methane, CH4, in oxygen?
Calculate How many grams of pure, solid sodium hydroxide are needed to make 500 mL of 0.15M NaOH solution and also express the answer in just 2 significant figures?
what is the heat flow of hot water added to cold water? What is the heat flow of the cold water? hot water was 52.5 C the cold water was 21.7 C the final temperature was mass of cold water was 49.35g
Calculate the entropy change when argon at 25 °C and 1.00 bar in a container of volume 0.500 dm3 is allowed to expand to 1.000 dm3 and is simultaneously heated to 100 °C.
Description of Chemical Reactions, Why when heating and cooling three different separate substances in open containers does the mass change in two of them (one loss mass; the other gained mass) but stays the same in the third when it is known that..
If the heat of combustion for a specific compound is -1390.0 kJ/mol and its molar mass is 61.39 g/mol, how many grams of this compound must you burn to release 821.90 kJ of heat.
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