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Conjugated diene addition reaction
a) When HCl is added to 1,3-butadiene either 3-chloro-1-butene or 1-chloro-2-butene forms. Which product is more stable? Explain.
b) Explain why at low temperatures, e.g. -80oC, when HCl is added to 1,3-butadiene the major product is 3-chloro-1-butene.
c) Explain why at +80oC when HCl is added to 1,3-butadiene the major product is 1-chloro-2-butene.
d) 3-chloro-1-butene is converted to 1-chloro-2-butene at +80oC, i.e. give the mechanism for the conversion. (Note: AlCl3 can be used to catalyze the conversion.)
a tank with a volume of 1.00M3 is filled with air at 0 degrees to 20 times its atmospheric pressure. How much volume will occupy at 1 atom and room temp?
In which compound does sulfur have the highest oxidation number a)Na2S2O3 b)NaHS c)H2S d)KHSO3 e) CuSO4
A gaseous mixture of O2, H2, and N2 has a total pressure of 1.50 atm and contains 8.20 g of each gas. Find the partial pressure of each gas in the mixture.
At a particular temperature, K 3.75 for the reaction SO2(g) + NO2(g) SO3(g) + NO(g) If all four gases had initial concentrations of 0.800 M
calcutate the molecular weight of surfur if 35.5 grams of sulfur dissolve in 100 grams of CS2 to produce a solution that has a boiling point of 49.48c.
a 43 L tank contains a gas under a pressure of 369 atm. What volume would the gas occupy at the same temperature at 710 torr of pressure?
Distilled water in the same tube gave a reading of +0.016 degrees. Calculate the specific rotation for the compound.
How long will it take 10.0 mL of oxygen gas to effuse through a porous barrier if it has been observed that 81.7 minutes are required for 10.0 mL of Cl2 gas to effuse through the same barrier?
Helium is compressed isothermally and reversibly at 100 celcius from a pressure of 2 to 10 bar
At 700 K the equilibrium constant for the reaction CCl4(g) C(s) + 2 Cl2(g) is Kp = 0.76. A flask is charged with 2.00 atm CCl4, which then reaches equilibrium at 700 K.
If a sodium hydroxide solution were added to a solution containing lead(II) ions, sodium ions, nickel(II) ions and potassium ions, which ion(s) would remain in the supernatant?
Which element requires the least amount of energy to remove the most loosely held electron from a gaseous atom in the ground state?
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