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Compounds A and B absorb in the ultraviolet region. Compound A exhibits an absorption maximum at 267nm (a=157) and a shoulder at 312nm (a=12.6). Compound B has an absorption maximum at 312nm (a=186) and does not absorb at 267nm. A solution containing the two compounds exhibits absorbances (using a 1.00cm cell) of 0.726 and 0.544 at 267 and 312nm, respectively. What are the concentrations of A and B in mg/mL? Note: The aborptivity values are given in units of L/g.cm.
Calculate the entropy of unfolding of lysozyme at 25 oC, given that the difference in PCof unfolding is 6.28 kJ/mol/K at both 25 oC and 75 oC. Hint: consider a path of 25 oC (folded)?75.5 oC(folded) ?75.5 oC(unfolded) ?25 oC(unfolded).
What is the concentration of a solution of lithium carbonate containing 0.01 mol in 750 mL of solution? Give your answer to two significant figures and include the units as mol L-1 ie 0.36 mol L-1
Use Henderson Hassalbalch equation to calculate how much HCl must be added to a liter of buffer that is 1.5 M in acetic acid and 0.75M in sodium acetate to result in a buffer pH of 4.10? Ka = 1.8 x 10-5
Find a) the average speed, b) the root-mean-square speed, and c) the most probable speed of these particles. Explain your results
Dipole moment, Formaldehyde has a very large dipole moment (2.33 Debye) whereas carbon monoxide has a very small dipole moment (0.11 Debye)
Calculate the hydrogen ion concentration for an aqueous solution that has a pH of 3.45.
Calculate the resulting CO2 concentration in the atmosphere 30 years from now assuming that we will use only coal to generate electricity. Assume efficiencies of 40% for power plants.
Calculate the formula of a compound, given that 55.85 g of iron combines with 32.06g of sulfur.
Calculate the numbers of moles of 2-butanol that needed to dissolved in ethenol(125gms) just to form 12 m 2 butanol soln also find out mass of 2-butanol ?
A student evaporated 100.0 mL of a saturated TlCl solution and found the solid TlCl she recovered weighed
the total pressure in the container is 3.70 atm . Calculate the partial pressure of each gas in the container
Draw the structure of a phosphodiacylglycerol that has hexadecanoic acid and 9-octadecenoic acid
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