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1. Draw a detailed mechanism for the FeBr3-catalyzed reaction of the ethylbenzene with bromine, and show why the sigma complex (and the transition state leading to it) is lower in energy for substitution at the ortho and para position than it is for substitution at the meta position. 2. Styrene (vinylbenzene) undergoes electrophilic aromatic substitution much faster than benzene, and the products are found to be primarily ortho- and para-substituted styrenes. Use resonance forms of the intermediates to explain these results. 3. Propose a detailed mechanism for the bromination of ethoxybenzene to give o- and p-bromoethoxybenzene. 4. Draw all the resonance forms of the sigma complex for niraion of bromobenzene a he ortho, meta, and para positions. Point out why the inermediate for meta substitution is less stable than the other two.
Draw the Lewis structure for each of the following molecules or ions, and predict their electron-domain and molecular geometries.
If 2.55 mol of ethane (C2H6) undergo combustion according to the unbalanced equation C2H6 + O2 -→ CO2 + H2O , how much oxygen is required? Answer in units of mol.
0.755 mole of bismuth oxide reacts with an excess of carbon to form bismuth metal according to the following reaction: Bi2O3(s) + 3 C(s)-> 2 Bi(s) + 3 CO(g) How many moles of Bi form?
If the pressure of chloroform vapor in a flask is 154 mm Hg at 25.0°C, and the density of the vapor is 1.25 g/L, what is the molar mass of chloroform?
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 mg HCN per kilogram of air when inhaled.
An aqueous solution of KNO3 has a molal concentration of 1.099 mol kg-1. Its density is 1.0630 g mL-1. Calculate the molar concentration of KNO3.
Solid aluminum reacts with aq H2 SO4 to form H2 gas and aluminum sulfate. when a sample of Al reacts, 425 mL of H2 gas is produced at 24 degree celsius at a press of 744 mmHg. How man grams of Al reacted?
In the reaction BaCO3 + 2HNO3 -> Ba(NO3)2+CO2+H2O, what mass of Ba(NO3)2 can be formed by combining 55g BaCO3 and 26g HNO3?
170mL of an HCl solution with pH of 2.80 is added to 200mL of an HNO3 solution. The resulting pH is 1.40. What was the pH of the original HNO3 solution
The solubility of sodium chloride in water is 35.7 grams per 100 mL at 0 degrees celsius. What is the maximum amount of sodium chloride that will dissolve in 250 mL of water at 0 degrees celsius?
How much heat (in ) is required to warm 12.0 g of ice, initially at -11.0 degrees C, to steam at 111.0 degrees C? The heat capacity of ice is 2.09 and that of steam is 2.01 J/gC.
calculate the kg mix- ture from the mixer, kg water evaporated, and kg jam produced.
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