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A tree killed by being buried under volcanic ash was found to have a ratio of carbon-14 atoms to carbon-12 atoms of 4.3 × 10-14. The rate constant of the C-14 → C-12 decay is k = 1.21 × 10-4 yr-1 and the ratio of carbon-14 to carbon-12 is 1.2 × 10-12 in a contemporary sample. Hydrogen sulfide burns in oxygen to form sulfur dioxide and water. If sulfur dioxide is being formed at a rate of 0.43 mol L-1 s-1, what are the rates of disappearance of hydrogen sulfide and oxygen? The decomposition of N2O5 has an activation energy of 103 kJ/mol and a frequency factor of 4.3 × 1013 s-1. What is the rate constant for this decomposition at 25 celsius and 373 K The decomposition of urea, (NH2)2CO, in 0.10 M HCl follows the equation (NH2)2CO(aq) + 2H+(aq) + H2O 2NH4+(aq) + CO2(g) At 65°C, k = 5.84 × 10-6 min-1 and at 75°C, k = 2.25 × 10-5 min-1. If this reaction is run at 85°C starting with a urea concentration of 0.0087 M, how many minutes will it take for the urea concentration to drop to 0.0012 M? If it takes 78.7 min for the concentration of a reactant to drop to 20.0% of its initial value in a first-order reaction, what is the rate constant for the reaction in the units min-1? The decomposition of acetaldehyde, CH3CHO, was determined to be a second order reaction with a rate constant of 0.0771 M-1 s-1. If the initial concentration of acetaldehyde is 0.225 M , what will the concentration be after selected reaction times? after 30 min? after 180 min?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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