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Derive a relation for ( hint: Maxwell's relations will be helpful) to determine how entropy will change with pressure at constant temperature (δS/δp)t for a gas that behaves according to the following equation of state PV = nRT/a + P/b, where a and b are empirically determined constants for a given gas.
Integrate your solution to solve for an equation for ?S and answer the following question.
Compare the proposed reaction mechanism for the sodiumhypochlorite oxidation of cyclohexanol with that involved in thechromic acid oxidation. Do you notice any similarities?
Before investigating the scene, the technician must dilute the luminol solution to a concentration of 5.00×10^-2 M. The diluted solution is then placed in a spray bottle for application on the desired surfaces.
The lattice energies of FeCl3, FeCl2, and Fe2O3 are (in no particular order) -2631 kJ/mol, -5339 kJ/mol, and -14,774 kJ/mol. Match the appropriate formula to each lattice energy.
What weight of sodium carbonate (Na2CO3) and sodium bicarbonate (NaHCO3) are required to make 500 mL of 0.2 M buffer, pH 10.70 (pK1 of H2CO3 is 6.10; pK2 = 10.30)
Butanoic acid has a partition coefficient of 3.0 favoring benzene when distributed between water and benzene. Determine the formal concentration of butanoic acid in each phase when 100mL of 0.10 Maqueous butanoic acid is extracted with 25mL of ben..
Which alkyl bromide will react the fastest with sodium iodide in acetone: 1-bromobutane, 2-bromobutane, or 2-bromo-2-methylpropane. Which alkyl bromide will react the slowest. Explain how the structure of the alkyl halide affects the rate of an SN..
aqueous HF and treated with nitron solution to precipitate a mixture of nitron tetrfluoroborate and nitron nitrate weighing 1.322 g. Find the weight percent of Mg in the original mixture.
A reaction mixture initially containing 0.520 M H2S and 0.520 M SO2 was found to contain 1.0 x 10 -3. A second reaction mixture at the same temperature initially contains 0.245 and 0.335. calculate the equilibrium concentration of H2O in the secon..
An aqueous NaCl solutions is made using 112 g of NaCl diluted to a total solution volume of 1.0 L. Calculate the molarity, molality and mass percent of the solution
how many moles of HNO3 are present in 33.0 mL of a 4.70M solution ?
What will be the pH change when 23.0 mL of 0.100 M NaOH is added to 80.0 mL of a buffer solution consisting of 0.159 M NH3 and 0.183 M NH4Cl
what is the composition of the vapor of a pentane-hexane solution that has a vapor pressure of 357 torr at 25c vapor
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