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In a time-of-flight mass spectrometer an ion having m/z of 22,000amu is accelerated with a voltage of 2500 V. The drift tube is 2.00 meters long.
1. Explain how much time is required for the ion to reach the detector?
2. In the MS configuration known as MALDI_TOF, the sample is usually mixed with a "matrix". Explain what is typical matrix material, define what is the purpose, and what advantage does MALDI have over other ionization methods
Why is it not possible to use acetic acid rather than formic acid in the Eischwieler-Clarke reaction. Look at the mechanism step involving transfer of a hydride (hydrogen w/ a pair of electrons. What part of formic acid is missing in acetic acid?)
The volume of a manifold used to transfer gases is calibrated using Boyle's Law. A 0.251-dm3 flask at pressure of 697 Torr is attached and after system pumpdown,
Calorimetry is a method used to measure changes in enthalpy, or heat, that occur during chemical processes. Two common calorimeters are constant-pressure calorimeters and constant-volume (or "bomb") calorimeters
One mole of ideal gas undergoes a three-step process. In step one: the gas expands isothermally and reversibly from state 1 to state 2. In step two: the gas is cooled isochorically yielding state 3.
Explain what is the poh of a solution made by mixing 100 ml of 010 m naoh, 50 ml of .0035 M KOH, and 25 ml of .0125 M LiOH
Predict the electron configuration of an octahedral d4 complex with (a) strong field ligands and (b) weak field ligands, and state the number of unpaired electrons in each case.
Use the cell potential for the Pb-PbI2 cell and the known [Pb2+] to calculate the [Pb2+] in equilibrium with PbI2.
Elliptical holes estimate the angle of entry : Cos A bullet hole in a wall at a crime scene is elliptically shaped. The loner dimension is 20 mm and the shorter dimension is 14 mm. What is the angle of entry?
a solution contains both copper ii and nickel ii. the absorbance of this solution at 394 nm is 0.175 while at 810 nm
Codeine (C18H21NO3) is a narcotic pain reliever that forms a salt with HCl. What is the pH of 0.069 M codeine hydrochloride (pKb of codeine is 5.80)
Enter the coefficient for each compound, seperated by commas, in the order in which they appear in the equation (e.g., 1,2,3,4,5,6,7).
Consider the reaction CaCN2 + 3 H2O → CaCO3 + 2 NH3 . How much CaCO3 is produced if 47.5 moles NH3 are produced
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