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Consider a system composed of a solid phase of calcium carbonate (CaCO3); a solid phase of calcium oxide (CaO); and a gaseous phase consisting of a mixture of CO2, CaCO3 vapor, and CaO vapor; all three constituents being present initially in arbitrary amounts. These are the substances that are present in a limekiln, where the reaction occurs.
CaCO3 CaO + CO2
(a) How many components are there, and what is the variance?
(b) Assuming the gaseous phase to be a mixture of ideal gases, show that
PCaOPCO2/PCaCO3 = K.
(c) If solid CaC03 is introduced into an evacuated chamber, how many components are there, and what is the variance?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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