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A compound A has prominent infrared absorptions at 1050, 1786, and 1852 cm-1 and shows a single absorption in the proton NMR spectrum at d 3.00. When heated gently with methanol, compound B, C5H8O4, is obtained. Compound B has IR absorptions at 2500-3000 (broad), 1730, and 1701 cm-1, and its proton NMR spectrum in D2O consists of resonances at d 2.7 (complex splitting) and d 3.7 (a singlet) in the intensity ratio 4:3. Give the structures A and B, omitting stereochemistry.
Methane gas is compressed from 22. L to 2.5 L at a constant temperature. The final pressure is 18.1 atm. What was the original pressure?
Analyzing a new reaction Consider the following elementary steps that make up the mechanism of a certain reaction: 2X -> Y + Z Y + L -> M + Z Part A What is the overall reaction
if 25.0 mL of 0.125 M HCl is neutralized by exactly 14.8 mL of NaOH, what is the concentration of the base?
How does one predict the regiochemistry of the products of aromatic reactions like nitration? What factors are responsible for the product ratios seen in such reactions?
Calculate the Triangle H degree f for calcium cyanamide.
What is the maximum number of electrons that can be identified with each of the following sets of quantum numbers? In some cases, the answer may be "none."
Hydrazine derivatives are commonly used in rocket fuels. Combustion of N2H4 produces N2(g) and H2O(g). When 1.00 g of N2H4 is burned in a bomb, DT = 3.51 oC. If C = 5.51 kJoC-1, what is the quantity of heat evolved? What is DH of this reaction?
Critically evaluate your evidence on whether the limonene isolated from orange peels
An aqueous solution is 35 % by mass methylamine (CH3NH2) and has a density of 0.85 g/cm3. What is the pH of the resulting solution if 50 mL of this solution is diluted
The most probable mechanism of reactivity for the solvolysis of tertiary butyl chloride is a)Sn1 b)Sn2 c)E1 d)E2. I performed the experiment and benzyl chloride (primary) and teriaty butyl chloride (tertiary) ran the same amount of time. 2-chloro-..
One of the steps in purifying silicon involves reacting the intermediate silicon tetrachloride with steam to produce high-purity silicon dioxide and hydrogen chloride gas
Choose one of the non-heme based oxygen transport proteins (i.e. not hemoglobin or myoglobin). Sketch the oxygen binding site environment
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