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An ion exchange column is used to capture a protein from a very dilute solution. Band broadening is controlled by intraparticle pore diffusion. The adsorption isotherm is essentially rectangular. The adsorption capacity is very high. Be as quantitative as possible in answering the following questions. Include sketches of the breakthrough curves for each case.
a. What happens to the time at which the mid point of the breakthrough curve exits the column if the feed concentration is halved?
b. What happens to the time at which the mid point of the breakthrough curve exists the column if the particle size is halved but the adsorption isotherm and column size stay the same?
If a total of 13.5 mol NaHCO3 and 4.5 mol of C6H8O7 react, how many moles of COs and NA3C6H5O7 will be produced? 3NaHCO3(aq) + C6H8O7(aq) -> 3CO2(g) + 3H2O(s) + Na3C6H5O7(aq)
At 373 K, Keq = 2.39 for the following reaction: SO2Cl2(g) = SO2(g) + Cl2(g) In an equilibrium mixture of the three gases, the partial pressures of SO2Cl2 and SO2 are 3.31 atm and 1.59 atm, respectively.
Calculate the mass of CuS produced and the concentration of H+ ion produced by bubbling H2S into 1.00 L of 0.10 M CuCl(aq) solution.
Calculate the pH at the beginning of a titration of 50.00 of 0.005M HA (Ka=2.0*10^-2) with NaOH solution. If the quadratic equation is assumed to be accurate
A hypothetical element Z has two stable isotopes: Z-46 = 46.046 u 64.08% Z-51 = 50.826 u 35.92% What is the average atom weight of the element?
Determine what is the observed rate for the given reaction - empirically determined rate
What is the boiling point of a 0.800 molal solution of sugar in water? Kb = 0.512C/m for water. Sugar does not dissociate in solution and pure water boils at 100C.
caclculate the number of grams of Fe formed when 0.300kg of Fe2O3 reacts.
Calculate the equilibrium constant KP if the total pressure is 2.6 atm at that temperature.
A solution of ethanol (C2H5OH) in water is prepared by dissolving 58.0 mL of ethanol (density = 0.79 g/cm3) in enough water to make 235.0 mL of solution. What is the molarity of the ethanol in this solution?
A flask contains 0.430 of liquid bromine, . Determine the number of bromine molecules present in the flask
Suggest a simple chemical test that would distinguish between the following compounds. State what you would see: a) n-pentane and 1-pentene
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