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An unavoidable side reaction of alkyl halides with active metals which lowers the yield of Grignard reagents is called coupling.
2 RX + Mg --------> R-R + MgX2
Although the mechanism of the coupling process is not well understood, it is known that ratre appears to depend on the square of the concentration of the halide. With this in mind, explain the reason for the sequaence of addition of the ether solution employed at the beginning of the formation of the Grignard reagent in the experimental procedure above.
A 1.800 g sample of octane, C8H18, was burned in a bomb calorimeter whose total heat capacity is 11.66 kJ/°C. The temperature of the calorimeter plus contents increased from 20.01°C to 29.99°C. What is the heat of combustion per gram of octane?
What is the hybridization of the nitrogen orbitals predicted by valence bond theory?
What is the ionization energy of rubidium atoms in kJ/mol if light with lamda=58.4nm produces electrons with a velocity of 2.450*10^6m/s? ( the mass ofan electron is 9.109*10^-31kg)
Rank the following solvents in order of increasing polarity: Acetone, Petroleum ether, methanol, ethanol, dichloromethane
At high temperatures, ammonia can react with oxygen according to the following unbalanced reaction: NH3 + O2 ---> NO + H2O If 5.76 moles of NH3 react with 12.2 moles of oxygen
There are two carboxylic acid functions in 3-nitrophthalic acid. The pKa of the acid function at the 2-position is approximately 2, whereas that at the 1-position is about 3. Which of the two is the more acidic and why
the temperature decreases by 0.2010 K. Calculate the molar heat of solution of KCN.
Thallium has an average atomic mass of 204.3833 u. It has two naturally occuring isotopes, 203Tl (with a mass of 202.9723 u) and 205Tl (with a mass of 204.9745 u). Find the percent abundance of the two isotopes, to ±0.001%.
If you used 0.165 mL of acetic anhydride, and 0.167 g of p-aminophenol. How many moles of the non-limiting reageant remained after the reaction was complete?
how many liters of C6H14(l) measured at 20 degC must be burned to provide enough heat to warm 26.9m^3 of water from 17.7 to 32.6degC .
In the preparatoin of a new pain reliever calls for 1.8 moles of an organic compound with fomula Na2(CH2CO2H)2 NCH2CH2(CH2CO2)2. How many grams of this compound should be weighed out for the reaction
Write out a complete reaction mechanism for the synthesis of the 1,2-diphenyl-1,2-ethanediol acetal from 1,2-diphenyl-1,2-ethanediol and 2,2-dimethoxypropane in the presence of acid
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