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Duplicate 0.50 g samples of a finely powdered gold ore are digested in an HCl/HNO3 mix and evaporated to dryness. Each sample is then treated with an additional 15 mL of HCl and diluted with an additional 40 mL of water. To one sample a 1.00 ml volume of a gold standard containing 5.0 ug/mL of gold is then added. Both samples are then treated with 5 mL of concentrated HBr to produce a gold bromide complex, and this is then extracted into 5 mL of methylisobutyl ketone. The atomic absorption signals were A=0.22 for the unspiked sample and 0.37 for the sample spiked with the additional gold standard. Assuming that the signal is linear over the measured absorptions, what is the concentration of gold in the original sample in ug/g?
The carbonyl carbon of an aldehyde, ketone, carboxylic acid, or ester cannot be a stereocenter. Why or why not
H2SO4, for the first step instead of concentrated HNO3 . What changes will be observed for the initial reaction with copper metal?
If 285.5 mL of SO2 reacts with 158.9 mL of O2 (both at 315K and 50.0 mmHg) what is the limiting reactant and theoretical yield of SO3
If a pipette was incorrectly calibrated so that it transfers 5% too much solution, would the density you calculated for the liquid tend to be larger or smaller then the correct value. explain.
What is the molecular equation, total ionic equation, and net ionic equation for Cu(NO3)2 and NaOH
If 29.8 mL of 0.102 M acid with a Ka of 0.000015 is titrated with 0.107 M NaOH solution, what is the pH of the titration mixture at halfway to the equivalence point?
The specific heat of liquid water is 4.184 J/g. degree C. Calculate the energy required to heat 10.0 g of water from 26.5 degree C to 83.7 degree C.
AMines can be made by the reduction of nitriles, which in turn can be made from an alkyl halide. Draw the structures of a starting alkyl bromide and the intermediate nitrile that would be used in the synthesis
400cm3 of glycerol, C3H8O3 (density= 1.26 g cm-3) is added to a kilogram of water. What is the mole fraction of C3H8O3 in the solution?
A gaseous mixture of O2 and N2 contains 39.8% nitrogen by mass. What is the partial pressure of oxygen in the mixture if the total pressure is 585mmHg
a sample of gas contains 0.2000 mol of c2h4g and 0.2000 mol of br2g and occupies a volume of 13.7 l. the following
What is the pH of a buffer that results when 0.50 mole of Na3PO4 is mixed with 0.75 mole of HCl and diluted with water to 1.00 L? The acid dissociation constants for phosphoric acid
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