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The rxn 2NO + O2 --> 2NO2 is believed to occur by the mechanism 2NO--> N2O2 k1 N2O2-->2NO k-1 N2O2+2-->2NO2 k2 ) Assume N2O2 to be in a steady state and derive the rate equation in terms of [NO] and [O2] as well as k. b) Under what conditions does the rate equation reduce to second-order kinetics in NO and first kinetics in O2
Calculate Gibbs free energy and determine the type of thermodynamic reaction and what type of thermodynamic reaction is shown.
Consider hte boiling of a liquid such as water in a frictionless piston and cylinder device computer the work obtained from the psiton when 1 kg of liquid water is vaporized to steam at 100 degrees C
Draw the Lewis Structure and make a rough three-dimensional sketch of each species.
Compare the length of a column of mercury to that of a column of water required to produce a pressure of 1.0 bar. the densities of mercury and water at 0C are for mercury 13.596g/cm^3 and for water .99987g/cm^3.
whats the amount of heat required to raise the temperature of 165 g of water from 12.0 C to 88.0 C (sp. heat of H20(l)= 4.18 J/g)
Formulate a reaction mechanism to show how, with excess acetic anhydride ,2-methyl benzisoxazinone might be formed.(Hint: acetylation of the amino group should occur first). How many moles of acetic anhydride are consumed in this reaction?
How much heat is required to warm 12.0 g of ice, initially at -11.0 C, to steam at 113.0 C?
How is the equilibrium yield of C6H12O6 affected by each of the following? 6 CO2(g) + 6 H2O(l) + HEAT C6H12O6(s) + 6 O2(g) (a) increasing PCO2 increases decreases no effect
the element neptunium possesses 93 electrons and weighs 237 amu. Calculate the contribution (in %) of its electrons to its total mass.
All numerical answers must be reported to the correct number of significant figures. What volume of 1.000 M LiCl must be diluted with water to prepare 250.0 mL of 0.100 M LiCl
The temperature of the water rose t oa final temperature of 27.84 C. Neglecting heat loss to the room and the heat capacity of the beaker itself, what is the specific heat of the alloy?
For each species listed, indicate the hybrid orbital set (sp2, sp3d, etc) employed by the central atom
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