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Dichlorodifluoromethane, also known as Freon-12 or R-12, was a commonly used refrigerant prior to the mid-1990s (when its production was banned in the US due to concerns about its effect on the ozone layer). Given that the constant pressure heat capacity of R-12 is 74 J·mol-1·K-1, determine the following:
a) The efficiency of a Carnot refrigerator operating with R-12 between 25.0 ºC and 5.0 ºC.
b) The energy (in kJ) that is removed as heat from this system when the Carnot refrigerator from part a) contains 340. g of R-12. Assume the heat is removed in a constant pressure process.
c) Compare your answer from part b) to the energy removed as heat from this system if the Carnot refrigerator contained an equal mass of air (Cp,m = 29.1 J·mol-1·K-1, molar mass ?29 g·mol-1). Do your answers show why R-12 is/was a superior coolant to air? Why or why not?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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