Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
We consider the transition state of a reaction to be a non accumulating transitory state at a critical point in a reaction. A+B-->X -->P where X is the transition state. X also has the double dagger symbol but I can't make it so I just used x. Also from A+B to X is reversible. K1 is from A+B->X k-1 is from X->A+B. And k2 is from X->P
A) Write d[X]/dT in terms of the concentrations of the relevant species
B) Derive the relationship that the effective rate constant of the reaction K is the same as (d[P]/dT)/([A][B]) takes the form k= k2 exp(-deltaG/RT) Where deltaG(these deltaG are with double dagger )is the standard free energy difference between the free energies of the transition state and reactant states A and B. Please make and state clearly any assumptions that are appropriate in deriving this result.
C) how does the effective rate constant of the reaction (k) depend on the pressure? Derive a relationship for the change in the natural log of the effective rate constant (ln k) vs some small pressure perturbation. Assume that k2 does not change with pressure.
D) if the transition state has a smaller volume than the reactants (deltaV double dagger < 0) does the effectice rate constant of the reactant increase or decrease when the pressure is increased?
Draw the structure of the product that results from the reaction of excess hydrogen gas in the presence of a nickel catalyst:
draw the Lewis structure with all bonds and lone pairs (b) indicate directions in all bond dipoles (c) indicate the molecular dipoles and (d) indicate the shape of each molecule.
A 10.00 mL sample of a solution of hydrofluoric acid,HF, is diluted to 500.00 mL. A 20.00 mL sample of the diluted solution requires 13.51 mL of a 0.1500 M NaOH solution to be titrated to the equivalence point.
Radioactive nitrogen-13 has a half-life of 10 minutes. After 40 minutes, how much of this isotope would remain in a sample that originally contained 96 mg?
How does the enthalpy change for the neutrlization of hydrochloric acid compare to the enthalpy change for the neutralization of aceitc acid. Explain any similarities or differences.
A gas sample containing N2 and O2 was found to contain 72% N2. If the pressure of the sample was 2.0 atm, what is the partial pressure of O2?
How many moles of Na and Cl2 are needed to make 7.3 moles of NaCl? Use the balanced equation 2Na + Cl2 --> 2NaCl
it decomposes into CO gas and Cl2 gas. If 12.5g of COCl2 is initially placed in a 2.20L container at 575K, calculate the concentration of CO at equilibrium. Kc= 2.50 * 10^-3 at 575K.
What would be the expected effect on yield if only one mole of diethylamine per mole of alpha-chloro
Bulb A with volume of 500 mL initially contains N2 at 0.7 atm pressure and 25?C. Bulb B, with volume of 800 mL initially contains O2 at 0.5 atm pressure and 0?
If the mass of the Co(NO3)2*6H20 obtained to prepare the stock solution had been more than the mass that you recorded would the concentration of the unknowns have been too high
If 21 mL of 6.0 M H2SO4 was spilled, what is the minimum mass of NaHCO3 that must be added to the spill to neutralize the acid?
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +1-415-670-9521
Phone: +1-415-670-9521
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd