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1-Butanol and chlorobenzene form a low-temperature azeotropic system. The mole fraction of 1-butanol in the liquid (X) and vapor (Y) phase at 1.00 atm is given below for a number of boiling temperatures [H. Artigas et al, J. Chem. Eng. Data 1997, 42, 132].
T / K 396.57 393.94 391.60 390.15 389.03 388.66 388.57X 0.1065 0.1700 0.2646 0.3687 0.5017 0.6091 0.7171Y 0.2859 0.3691 0.4505 0.5138 0.5840 0.6409 0.7070
Pure chlorobenzene boils at 404.86 K.
a) Construct the chlorobenzene-rich portion of the phase diagram from the data.
b) Estimate the temperature at which a solution whose fraction of 1-butanol is 0.300.
c) State the compositions and relative proportions of the two phases present after a solution initially at thjis mole fraction (0.300) is heated to 394.94.
Draw the crystal-field energy level diagram for the 3d obitals and show the placement of d electrons assuming this is a weak-field complex ion.
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If all four gases had initial concentrations of 0.650 M, calculate the equilibrium concentrations of the gases.
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