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The next 6 questions involve the calculation of concentrations of the molecular and ionic species in an aqueous solution that has an analytical composition of 0.060 M KH2PO4 + 0.460 M K2HPO4.
NOTE: The Ka's for the three acidic protons of phosphoric acid H3PO4 are: 7.11 x 10-3, 6.32 x 10-8, and 4.5 x 10-13. It may be helpful to write out the three dissociation reactions along with their Ka's and pKa's before starting these problems.
1) What is the concentration of K+ in molarity?
2) What is the concentration of OH-?
These two solutions will be added together into a beaker to create one solution. Adding them together cause them to dilute each other. Calculated the new molarity of HX. Give your answer to four decimal places.
An automobile gasoline tank holds 35 kg of gasoline. When the gasoline burns, 88 kg of oxygen is consumed, and carbon dioxide and water are produced.
Explain for which of the following species resonance is an important property: HONO, HONO2, N3-, NO2-, NO2.
You are using a Geiger counter to measure the activity of a radioactive substance over the course of several minutes. If the reading of 400. counts has diminished to 100. counts after 35.2 minutes, what is the half-life of this substance
If all 0.44 gigatons CO2 remain in the atmosphere and spread around the atmosphere evenly, what concentration in ppm would it constitute?
Explain why a determination of the rate law can never prove a proposed reaction mechanism but can sometimes disprove
If 110mg of fluorine-18, which has a half-life of 110min, is shipped at 8:00 a.m., how many milligrams of the radioisotope are still active if the sample arrives at the radiology laboratory at 1:30 p.m.?
Phosphorus pentachloride is used in the industrial preparation of organic phosphorus compounds. Equation 1 shows its preparation from PCl3 and Cl2.
Calculate the mass percent of copper(II) sulfate pentahydrate in the recovered sample.
As you may well know, placing metal objects inside a microwave oven can generate sparks. Two of your friends are arguing over the cause of the sparking, with one stating that the microwaves "herd" electrons into "pointy" areas of the metal object,
Calculate the pH of the buffer after the addition of 1.5 g of HCl (36.5 g/mol). (Ka of HNO2 = 7.1x10^-4.)
Calculate the concentration of magnesium and calcium in ppm. Record your answers as ppm Mg2+, and Ca2+ espectively. For each answer indicate the ppm as CaCO3 also.
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