Explain metals covalently bonded to benzene

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Metals Covalently Bonded to Benzene
I've noticed that my book does not mention metals as a possible substituent for mono-substituted benzenes, but it doesn't begin to explain why. Also I have had trouble finding reasons why online. Specifically I am interested to know why you don't see metals bonded to benzene with a covalent sigma bond. I am not interested in metal benzene complexes. As much in depth help that anyone can offer would be greatly appreciated.

Reference no: EM13133219

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