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ketones react with dimethylsulfonium methylide to yield epoxides by a mechanism that involves (1) an initial nucleophilic addition followed by (2) an intramolecular Sn2 substituition, Show the mechanism.
Nitrogen dioxide (NO2) cannot be obtained in a pure form in the gas phase because it exists as a mixture of NO2 and N2O4. At 25°C and 0.98 atm, the density of this gas mixture is 2.7 g/L.
What is the standard free energy change (kJ) for the following reaction at 499.0 K ? [Note: Answer should be expressed as "xxx.x", or with one sig fig after the decimal
a solution of 4.00 g of sodium carbonate is mixed with one containing 4.00 g of silver nitrate. after the reaction is complete, the solutions are a mixture of salts.
Calculate the standard Gibbs free energy and the equilibrium constant at 298 K and at 400. K for the reaction PbO(s) + CO(g) ? Pb(s) + CO2(g).
The protein needs to be in 1X buffer and in a total volume of 0.100 mL. You are given a 5mg/mL protein solution, a 20X sample buffer, and distilled water. How much of each wuld you mix together to make the required volume?
Use the Nutritional information on the food bag to calculate the calories per gram? How does this information compare to your information? How do you explain the discrepancy? How could you do the experiment differently to get a more accurate value..
How many liters of chlorine gas, measured at STP, would be produced by the electrolysis of molten sodium chloride using a current
what is the longest wavelength of radiation that possesses the necessary energy to break a nitrogen bond.
The molecule iodine monochloride ICl has a diple moment of 1.6 D and a bond length of 2.32 A. What is the effective charge on I in untis of electronic charge e
Determine the mass of carbon dioxide produced when .85 grams of butane reacts with oxygen according to the following equation : 2C4 H10 + 13O2 ->8CO2 + 10H2O
A copper tube is 1 inch in diameter and 2 feet long, it is filled with steel balls of 1 inch diameter. The space between the balls is filled with water. the specific gravity of the steel b all is 7.8. What is the bulk denisty of the contents of th..
A reaction inside a cylindrical container with a movable piston causes the volume to change from 14.0L to 21.0L while the pressure outside the container remains constant at 0.975 atm.
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