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When temperature and pressure confitions are not too severe, equations of state me be integrated explicitly to determine the fugacity of a gas. Derive an expression for ln(f/p) for a van der Waal's gas. (HINT: Wrtie van der Waals equation in virial form.) Use your equation to calculate (a) the fugacities and (b) the fugacity coefficients for methane at the following pressures: 0, 10, 1000, and 500 atmospheres. At what pressures are the fugacity coefficients equal to unity? at what pressures is the fugacity equal to 1.0000 atm?
This reaction is sometimes used to inflate life rafts, weather balloons, and the like, where a simple, compact means of generating H2 is desired. How many grams of CaH2 are needed to generate 16.0 L of H2 gas if the pressure of H2 is 750. torr at ..
Draw the Lewis structure for each including formal charges and describe in paragraph format how you went about solving the problem and making sure the answer was correct.
Calculate the work done if a gas is compressed from 8.1 L to 3.9 L at constant temperature by a constant pressure of 2.3 atm, and give your answer in units of joules.
At a certain temperature and pressure, one liter of CO2 gas weighs 1.95 g. What is the mass of one liter of C2H6 gas at the same temperature and pressure
For each of the following equilibria, use Le Chatelier's principle to predict the direction of reaction when the volume is increased.
Assuming complete dissociation of the solute, how many grams of \rm KNO_3 must be added to 275 \rm mL of water to produce a solution that freezes at -14.5 ^\circ {\rm C}? The freezing point for pure water
Place the following compounds in order of increasing strength of intermolecular forces. CH4, CH3CH2CH3, CH3CH3
Na3AlF6(l) 3 Na(l) + Al(l) + 3 F2(g) What is the concentration of F2 over a bath of molten cryolite at this temperature? a) 3 10-35 M b) 5 10102 M c) 6 10-74 M d) 8 10-312 M e) 8 1017 M
How many grams of dry NH4Cl need to be added to 2.30 L of a 0.100 M solution of ammonia,NH3, to prepare a buffer solution that has a pH of 9.00
Maria wants to plant a small tomato garden in her yard. She bought 25 tomato plants, and she has read that ideally tomatoes are planted in a square grid
the laboratory is dissolved in 95% ethanol, diluted with water, and titrated to a phenolphthalein endpoint with 17.3 mL of 0.114 M NaOH. What is the percent purity of aspirin in the sample?
Unlike translational degrees of freedom, the rotational partition function must be evaluated by summation, unless the high-temperature limit is obtained. What is the definition of the high-temperature limit for rotations?
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