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Scientists can use mutants to study metabolic pathways. These organisms have a mutation in a gene encoding a metabolic pathway enzyme that results in the inactivation of that enzyme. Saccharomyces cerevisiae (a yeast species) mutants are available that grow on fructose, but not glucose. Which of the following glycolytic enzymes is mostly likely affected?
a.phosphoglycerate kinase
b.enolase
c.pyruvate kinase
d. phostphoglycerate mutase
e. Phosphoglucose isomerase (phosphohexose isomerase or glucose-6-phosphate isomerase)
Explain why saturated sodium hydrogen carbonate is used to wash the organic layer in the Friedel Crafts Acylation.
Estimate the mass of water that must evaporate from the skin to cool the body by 0.50^circ C. Assume a body mass of 85 kg and assume that the specific heat capacity of the body is 4.0 {rm{J}}/{rm{g}}; cdot ;^circ {rm{C}}.
A chemist wants to prepare 0.65 M HCl. Commercial hydrochloric acid is 12.4 M. How many milliliters of the commercial acid does the chemist require to make up 1.48 L of the dilute acid?
A mixture consisting of 2.50×10!3 g of O2, 3.51×10!3 mol of N2, 4.67×1020 molecules of CO are placed in a vessel with a volume of 4.65 L at 15.4°C.
Consider the heterogeneous equilibrium process shown below. C(s) + CO2(g) 2 CO(g) At 700.°C, the total pressure of the system is found to be 3.20 atm. If the equilibrium constant KP is 1.52,
256 grams of sodium chloride reacts with an excess of calcium oxide. How many grams of sodium oxide are produced?
Write the structures of the following compoundsa) 2,2-dibromo-3,3-dichloro-5,5-difluoro-6,6-diiodobicyclo{2.2.1}heptane
How many grams (to the nearest 0.01 g) of NH4Cl (Mm = 53.49 g/mol) must be added to 550. mL of 0.906-M solution of NH3 in order to prepare
Assuming this mechanism is correct, which is the rate-determining step if the experimental rate law is first order in nitryl chloride?
What is the BOD concentration just downstream of the discharge point? (b) If the stream has a cross-sectional area of 10 m2, "what is the BOD concentration 50 km downstream? (BOD is removed with a first-order decay rate con- stant equal to 0.20/da..
calculate the heat in joules released by the dissolving salt. Assume that the specific heat of the solution is the same as thar of pure water(4.184J/g- celcius) and that the calorimeter is perfect.
(a)What is the coordination geometry about the vanadium ion incrystals of the alum? Write balanced equations for each reduction step
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