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Search the web for sites with particular periodic tables. Find one that gives thermodynamic data for the elements. Use the data given for the specific heat to test the law of dulong and petit. Find the molcular heat capacity in units. Does the law hold up? Can you distinguish a metallic element from a nonmetal this way? Metalloids?
Propose a reasonable reaction mechanism for the sodium hypochlorite oxidation of 3-heptanol. Give the IUPAC name of the expected product.
Show that the enthalpy of combustion of saturated hydrocarbons may be expectred to follow the relation
Molarity is only one of many ways to express concentration. Another is percent mass per volume or %(m/v). For example, vinegar usually contains about 5 %(m/v) acetic acid(5g acetic acid/100 mL vinegar)
If there's a mixture of O2 and N2, and the mol of N2 is 0.605 mol, and fraction (f) of O2 is 0.251; then, what is the mol of O2?
Sketch a molecular orbital energy level, show the symmetry for each one, and indicate how each orbital is formed from the group orbital of 2H atoms and the atomic orbitals of S atom.
2. 0.33g of KOH is dissolved in 350.0ml of ethanol and 1.45g of C2H5I is dissolved in 350.0ml of ethanol. Assuming the reaction is first order, when equal volumes of the two solutions are mixed, what is the initial rate at 40oC?
What is the molality of a solution in which 25 g of sodium chloride is dissolved in 2.0 kg of water
A sample of nitrogen gas occupies a volume of 3.87 liters at 52.8 oC and 2.11 atm. What will the new temperature (in °C) when the volume increases to 4.55 liters and the pressure remains constant?
A sample of H½O with a mass of 46.0 grams has a temperature of -58.0 àC. How many joules of energy are necessary to heat the steam from 100.0 àC to 114.0 àC if the specific heat of steam is 2.01 J/g àC?
The second virial coefficient of methane can be approximated by the empirical equation , where a = -0.1993 bar-1, b = 0.2002 bar-1, and c = 1131 K2 with 300 K
Suppose that you have a 2.0 L sample of hydrogen at 1.00 atm and 59°C. If you heat the sample to 84°C and it expands to a volume of 3.7 L, what will the final pressure be?
Determine the enthalpy change for the combustion of ammonium nitrate(NH4NO3)with decane (C10H22) in oxygen. Hf for C10H22= -249.7 kJ/mol
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