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For some enzyme reactions (for example, the hydrolysis of cAMP by phosphodiesterase in vertebrate retinal cones)the enzyme is present in large quantities,so that e0/s0 is not a small number.Fortunately,there is an alternate derivation of the Michaelis-Mentenrate equation that does not require that e= e0/s0 be small. Instead, if one or both of k-1and k2 are much larger than k1.e0, then the formation of complex c is a rapid exponential process,and can be taken to be inquasisteady state.Make this argument systematic by introducing appropriate nondimensional variables and then ?nd the resulting quasi-steady-state dynamics. (Segel,1988; Frenzen and Maini, 1988; Segel and Slemrod, 1989; Sneyd and Tranchina, 1989)
What volume in liters of O2(g) is required to form 46 L of CO2(g)? Assume both gases are measured under the same conditions.
A certain gas has a volume of 200 dm3 at 27oC and 2 atmospheres of pressure. What is its volume at STP?
Calculate the equilibrium partial pressures of all species when CO and Cl2, each at an intitial partial pressure of 1.53 atm, are introduced into an evacuated vessel at 600 K.
The pressure on 200 ml of oxygen gas changes from 380 mm hg to 760 mm hg. The temperature does not change. What is the new volume of the oxygen gas?
An object made of aluminum has a mass of 8.37g. When it was placed in a graduated cylinder containing 20.0mL of water, the water level rose to 23.1mL. Calculate the density and specific gravity of the object.
How do I calculate the product distribution calculations of the three peaks? Or the product ratios? The first peak was at 0.600, second at 0.95. Those are the retention times
Using the Grubbs test, decide wheter the value 216 would be rejected from the set of results 192, 216, 202, 195 and 204. G ( 95% confidence) : 1.463, 1.672, 1.822, 1.938, 2.032
calculate the minimum energy a photon must have to produce an electron hole pair in an extrinsic semiconductor of band gap 1.3 electron volts.
Benzene (C6H6) is a trace component of gasoline. What is the mole ratio of benzene to n-octane in the vapor above a solution of 35.0% benzene and 65.0% n-octane by mass at 25 degrees C
What is the maximum kinetic energy of a photoelectron ejected fromcesium by 555 nm light? Note that if the wavelength of light usedto irradiate the cesium surface becomes longer than 660 nm
The concentration of alkaline phosphate in the stock solution used in the experiment was .25mg protein/mL. Calculate the activity of the enzyme at Vmax as umole substrate hydrolyzed per minute per mg of enzyme protein.
E1 mechanisms a little clearer? maybe make a chart with simmilarities and differences and how to know which one is which?
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