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Please consider the reaction of 0.22M 2-iodopropane with tetramethylammonium fluoride (TMAF) in DMSO to give propylene. The reaction rate in the presence of 0.1M TMAF is 0.002 M/s, but it is 0.0058 M/s in the presence of 1.2M TMAF.
a. Given the data above, what is kE2 / kE1 , the ratio of rate constants for the E2 and E1 mechanisms?
b. When the ln( kE2 / kE1 ) is plotted vs. 1/T the resulting linear graph has the slope of - 4.8 and intercept of 6.1What is the difference in activation energies of the two mechanisms? For which mechanism are the reactive collisions more efficient?
Calculate the pressure of the gas mixture and the partial pressure of each constituent gas if the mixture is in a 11.0 L vessel at 27 degree celsius
A volume of 18.0 L contains a mixture of 0.250 mols N2 , 0.250 mols O2 , and an unknown quantity of He. The temperature of the mixture is 0 degrees C , and the total pressure is 1.00 atm.
At what ph would you carry out an electrophoresis experiement if you wanted to seperate a mixture of lysine
3H2 + N2 -> 2NH3. At 200 degrees C in a closed container, 1.00atm of nitrogen gas is mixed with 2.00atm of hydrogen gas. At equilibrium, the total partial pressure is 2.00atm.
Would it be a good idea for a person to take a couple of aspirin tablets before attending a cocktail party? Explain your reasoning. This needs to be from a chemistry stand point.
it decomposes into CO gas and Cl2 gas. If 12.5g of COCl2 is initially placed in a 2.20L container at 575K, calculate the concentration of CO at equilibrium. Kc= 2.50 * 10^-3 at 575K.
Brominated biphenyls (PBB) is created through an electrophilic aromatic bromization out of the hydrocarbon biphenyl.
A mixture of CS2(g) and excess O2(g) is placed in a 1.00 L reaction vessel at 100.0 degrees celcius and a pressure of 3.00 atm. A spark causesthe CS2 to ignite
A separate experiment is conducted in which 4.82 x 10-5 M CaI2(aq) is added to a solid solution of PbI2 at 20 oC. Qualify how the molar solubility changes
A balloon is partly inflated with 480 liters of helium at sea level where the atmospheric pressure is 996 mbar.The balloon ascends to a altitude of 3000 meters.
If 12.6 grams of iron (III) oxide reacts with 9.65 grams of carbon monoxide to produce 7.23 g of pure iron, what are the theoretical yield and percent yield of this reaction?
The molar absorptivities for methyl red in its acid form are 44640 M^-1cm^-1 @ 524 nm and 3860 M^-1cm^-1 @ 425nm and for methyl red in its base form are 740 M^-1cm^-1 @ 524nm and 18530 M^-1cm^-1 @ 425nm
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