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Explain, in detail, why a bromine radical is more selective than a chlorine radical during abstraction of a hydrogen on a hydrocarbon?
1. Imagine a researcher allowed the paper chromatogram to develop for far longer than necessary in the mobile phase, such that the solvent front ran into the top edge of the paper and the spots continued to move. Would the resulting Retention Factors be overestimated, underestimated or remain unaffected?Explain your reasoning.
2. Imagine a researcher stopped the development of the paper chromatogram before the solvent front had reached near the top of the paper. Would the resulting Retention Factors be overestimated, underestimated or remain unaffected? Explain your reasoning.
3. Imagine a researcher left the mobile phase sitting uncapped in the fumehood for an extended period of time, such that a large portionof the acetone evaporated. How would this, if at all, change the outcome of the experiment? Would Retention Factors be affected? Would the unknowns still be identifiable? Explain your reasoning.
Determine how many kgs of Ca are there in a 205-pound man If 1.4 percent of the mass of a human body is calcium(Ca)?
The density of benzene at 25.0 degrees C is 0.879g/cm3. What is the volume in liters of 2.5 kg benzene?
The temperature of the calorimeter plus contents increased from 21.12°C to 29.85°C. What is the heat of combustion per gram of octane? What is the heat of combustion per mole of octane?
Gasoline currently powers the majority of automobiles in the U.S. but electric cars have been touted as a way to reduce our dependence on gasoline as well as improve our air quality by reducing production of byproducts associated with gasoline com..
This solution was back-titrated with a 0.0440 M Ga3 solution until all the EDTA reacted, requiring 12.0 mL of the Ga3 solution. What was the original concentration of the V3 solution?
2NOCl(g) → 2NO(g) + Cl2(g) ,At 450 K the rate constant is 15.4 atm-1s-1. How much time (in s) is needed for NOCl originally at a partial pressure of 46 torr to decay to 25.8 torr.
The acid-dissociation constants of phosphoric acid (H3PO4) are Ka1 = 7.5 × 10-3, Ka2 = 6.2 × 10-8, 25) and Ka3 = 4.2 × 10-13 at 25.0 °C.
Physical propoerties and intermolecular forces, What type of intermolecular forces accounts for the following differences in each case?
A 20.00mL sample of H3Y was titrated with 0.1000 M NaOH. The first equivalence point was reached after the addition of 14.98mL of base. The second equivalence point was reached after the addition of 30.03mL.
A sample of gas occupies 1.55L at STP. Remember, pressure at STP is 1.0 atm. What will the volume be if the pressure is increased to 50 atm while the temperature remains constant
Give the overall balanced reaction, and determine E° for the galvanic cells. Assume that all concentrations are 1.0 M and that all partial pressures are 1.0 atm.
Mehtanol-water solutions behave as essentially ideal solutions (the activity coefficients which measure deviation from ideality are equal to or close to one).
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