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A critical reaction in the production of energy to do work or drive chemical in biological systems is the hydrolysis of adenosine triphosphate, ATP to adenosine diphosphate ADP as described by ATP(aq) + H20(l) ----> ADP(aq) + HPO4^2- (aq) for which ?G°rxn = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of ?Grxn in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.40 mM, and [HPO42-] = 5.0 mM. change in G rxn=________kJ/mol
Calculate the difference in pressure between methane and an ideal gas under these conditions. The van der Waals constants for methane
A certain second-order reaction (B--->products) has a rate constant of 2.00×10^-3 M^-1 s^-1 at 27 Celsius and an initial half-life of 214 s. What is the concentration of the reactant after one half-life
Calculate the change in molar Gibbs energy, ?Gm, of liquid mercury initially at 1.00 bar pressure if a pressure of 1000. bar is applied to it. The process occurs at the constant temperature of 25 ºC
the value of kf for cyclohexane is 20.0degcm and its normal freezing point is 6.6degc. a mass of 1.604 g of a waxy
when a metal was exposed to light at a frequency of 4.49 x 10^15 s^-1, electrons were emitted with a kinetic energy of 4.80 x 10^-19 J. What is the maximum number of electrons that could be ejected from this metal by a burst of light with a total ..
A saturated solution of an unknown solid reacted with AgNO3 to give a pale yellow precipitate and also reacted with Pb(NO3)2 to give a white precipitate.
Three gases (8.00 g of methane,CH4 , 18.0 g of ethane,C2H6 , and an unknown amount of propane,C3H8 ) were added to the same 10.0-L container. At 23.0 degrees celusis , the total pressure in the container is 4.40atm . Calculate the partial pressure..
A typical commercial-grade phosphoric acid solution is 75% phosphoric acid by mass, and has a density of 1.57 grams per milliliter. What are the molarity and molality of H3PO4 in this acid?
At 0.0 degrees C, if the volume of air is 2.5 mL and the pressure of the atmosphere that day is 805 mmHg, what is the number of moles of air.
Tests on human subjects along the East Coast of the United States in 1965 and 1966, following the era of atomic bomb testing, revealed quantities of about 1.71 pCi of plutonium radioactivity (alpha radiation) in a test subject. How many disintegra..
What is the conversion calculation for M to grams of KBr for the following: What mass of potassium bromide is contained in 135 mL of 0.251 M Kbr solution
The boiling point of a certain pure liquid is 53.0 C and the enthalpy of vaporization is 32.7 kJ/mol at this temperature. The entropy of vaporization for this liquid is: in J/K mol
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