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Problem
a) In the design of a chemical process, the specifications are such that the density and temperature are known for a fluid going through a throttling (expansion) valve. Determine an expression in terms of (T, P, V, Cp, Cv, α, KT) to calculate the density of the fluid after the expansion given that the temperature is known.
b) Estimate the density change for this fluid upon expansion. This fluid has a density of 7220 mol/m3 and is at 410 K. The temperature of the fluid after the expansion is 290 K. For this fluid, the average value of a between 290 and 410 K is 4.31 x 10-3 K-1. The value of KT is 3.49 x 104 bar-1 at 290 K and 3.71x10-2 bar-1 at 410 K. The value of Cv is 79 J/mol.K at 290 K and 109 J/mol.K at 410 K.
A hydrogen atom in its ground state absorbs a UV photon at a wavelength of 93.8 nm. It then re-emits a photon as it relaxes to the n=2 energy level.
Question- How much energy (in kilojoules) is released when 16.1g of steam at 112.5 C is condensed to give liquid water at 79.0 C? The heat of vaporization of liquid water is 40.67 kJ/mol, and the molar heat capacity is 75.3 J/(kJ*mol) for the liqu..
A chlorine atom can occupy one of the nine possible sites. When a bromine is added to the system it can occupy one of hte eight sites not already occupied by the chlorine
Describe in detail how you would make 50.0mL of a 0.100M Hydrochloric acid solution from concentrated (12.1M) hydrochloric acid
It is desired to inflate a baggie with a volume of 869 milliliters by filling it with hydrogen gas at a pressure of 0.847 atm and a temperature of 296 K. How many grams of H2 gas are needed? answer in g please
Calculate the number of grams of sulfuric acid present in the mixture after the reaction is complete.
An astrology-loving friend hypothesizes that people born in that week like horror movies more than other genres of movies. You decide to use the scientific method to test this hypothesis.
If 500 ml of 0.20 M NaCN is treated with 500 mL of an HOCl solution to produce a resultant solution with pH 7.00, calculate Mi for this HOCl solution. Show all pertinent work including reaction equations but not arithmetic.
A gas expands from 282 mL to 971 mL at constant temperature. Calculate the work done (in joules) by the gas if it expands against a vacuum.
Provide a structure for the following compound: EI mass spectrum: two molecular ions of about equal intensity at m/z = 180 and 182; IR: 1740 cm-1; 1H NMR: ? 1.30 (3H, t J = 7 Hz); ? 1.80 (3H, d, J = 7 Hz); ? 4.23 (2H, q, J = 7 Hz); ? 4.37 (1H, q, ..
A 2.0 L solution contains [Ag+] = 0.100 M and [Pb(2+)] = 0.100 M (Ksp = 1.8 * 10^(-10) for AgCl and Ksp = 1.8 * 10(-5) for PbCl2). Explain the metals are selectively precipitated by adding NaCl. Presume no volume changes.
Question- A fossil is found to have a 14C level of 87.0% compared to living organisms. How old is the fossil
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