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Carbon disulfide (CS2) is a toxic, highly flammable substance. The following thermodynamic data are available for CS2(l) and CS2(g) at 298 K:
(a) Draw the Lewis structure of the molecule. What do you predict for the bond order of the C - S bonds?
(b) Use the VSEPR method to predict the structure of the CS2 molecule.
(c) Liquid CS2 burns in O2 with a blue flame, forming CO2(g) and SO2(g). Write a balanced equation for this reaction.
(d) Using the data in the preceding table and in Appendix C, calculate ?H° and ?G° for the reaction in part (c). Is the reaction exothermic? Is it spontaneous at 298 K?
(e) Use the data in the table to calculate ?S° at 298 K for the vaporization of CS2(l). Is the sign of ?S°as you would expect for a vaporization?
(f) Using data in the table and your answer to part (e), estimate the boiling point of CS2(l). Do you predict that the substance will be a liquid or a gas at 298 K and 1 atm?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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