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Consider the dimerization 2A to A2, with forward rate constant ka and backward rate constant kb. (a) derive the following expression for the relaxation time in terms of the total concentration of protein [A]tot = [A] + 2[A2]: (1/tau^2) = kb^2 + 8kakb[A]tot (b) describe the computational procedures that lead to the determination of the rate constants ka and kb from measurements of tau for different values of [A]tot (c) use the data provided below and the procedure you outlined in part b to calculate the rate constants ka and kb, and the equilibrium constant K for formation of hydrogen-bonded dimers of 2-pyridone: [A]tot 0.500 0.352 0.251 0.151 0.101 tau 2.3 2.7 3.3 4.0 5.3
Bessemer converter is used for the manufacture of : Which is the formula of Haematite
What is the molar mass of the unknown gas? Express your answer to four significant figures and include the appropriate units.
A solution containing 3.47mM X (analyte) and 1.72 mM S (standard) gave peak areas of 3473 and 10222, respectively, in a chromatographic analysis. Then 1.00ml of 8.47mM S was added to 5.00ml of unknown X, and the mixture was diluted to 10.0ml. This..
A pound of coffee beans yields 30 cups of coffee (4 cups = 1 ). How many milliliters of coffee can be obtained from 1.0 of coffee beans.
The heat of vaporization of water in this temperature range is 2.40 kJ/g. The heat capacity of water is 4.184 J/g.K. Answer in grams of water
When boron triflouride is added to ammonia gas, does boron triflouride act as a lewis acid or a lewis base?
What volume (in liters) of 1.04 M KOH solution should be added to a 0.090 L solution containing 9.3 g of glutamic acid hydrochloride (Glu, FW=183.59; pKa1=2.23, pKa2 =4.42, pKa3=9.95) to get to pH 9.90?
Calculate the osmotic pressure of a solution containing 20.00mg of hemoglobin in 16.3mL of solution at 25 ? C The molar mass of hemoglobin
Calculate the free energy change for the following reaction and predict whether the reaction occurs spontaneously at 25 degrees celcius. H2(g)+CO2(g)-->H20(g)+CO(g); ?H=41.8 kJ, ?S=42.1 J/K
Cadaverine are 9.13 and 10.25. If the ends of these molecules look the same, why do they have different pkas?
The compound, an eight-carbon alkane, serves as the 100 octane standard for gasoline. It has five methyl groups, one quaternary carbon, tests negative for C-C double bonds and gives four monochloro substitution products
What must the concentration be, of each member of the buffering acid/base pair, if the reaction is expected to release 0.1 millimoles of H+?
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