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a) When HCL is added to 1,3-butadiene either 3-chloro-1-butene or 1-chloro-2-butene forms. Which product is more stable and EXPLAIN
b) EXPLAIN why at low temperatures, e.g. -80 °C, when HCl is added to 1,3-butadiene the major product is 3-chloro-1-butene.
c) EXPLAIN why at +80 °C when HCl is added to 1,3-butediene the major product is 1-chloro-2-butene.
d) 3-chloro-1-butene is converted to 1-chloro-2-butene at +80 °C, i.e. give the mechanism for the conversion. (Note AlCl3 can be used to catalyze the conversion).
Write the reaction and predict the major organic products(s) for each of the following reactions. Make sure to consider stereochemistry & regiochemistry, if applicable.
the volumetric flask during weighing by difference after recording the mass, how would it affect the final result for his calculated molecular mass of the metal carbonate?
Calculate the concentration of IO3- in a 3.02 mM Pb(NO3)2 solution saturated with Pb(IO3)2. The Ksp of Pb(IO3)2 is 2.5 × 10-13. Assume that Pb(IO3)2 is a negligible source of Pb2 compared to Pb(NO3)
How many kJ of energy are required to convert 258 grams of ice at 0°C to water (liquid) at 42.1°C? The following information is given for H2O.
Explain why the bond dissociation energy for the C-C sigma bond in propane is lower than the BDE for the C-C bond in propene.
You are asked to prepare an aqueous solution of ethylene glycol (HOCH2CH2OH) with a mole fraction of 0.142.
CH3OH burns in oxygen (O2) to from carbon dioxide (CO2) and water(H2O). Equal masses of ten grams of gaseous CH3OH and O2 are placed in an evacuated flask of five litres at the temperature of 25 degrees celsius.
Important information about Imidazole. The imidazole ring system has a great deal of aromatic character. Can you formulate two resonance structures that account for the characteristics?
Elements cannot be decomposed by chemical means, but can be decomposed by physical means.
what is the theoretical yield of zinc iodide, if a 2.0-g sample of zinc was used with 6.5 grams of iodine
Calculate the volume the gas will occupy if the pressure is increased to 1.88 atm while the temperature is held constant
How much heat is required to warm 223 g of ice from -44.3°C to 0.0°C, melt the ice, warm the water from 0.0°C to 100.0°C, boil the water, and heat the steam to 173.0°C?
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