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After the first deprotonation of maleic acid, an intramolecular hydrogen bond can form in the hydrogen maleate ion (HC4H2O4) but it cannot form in the case of fumaric acid deprotonation. Draw the structures of both deprotonated isomers and explain how the difference in cis and trans arrangements allow the single-deprotonated form of maleic acid to form a hydrogen bond with itself but fumaric acid cannot form a similar hydrogen bond when it has lost just one of its two acidic protons
Draw one planar structure each for the following compounds using dashed or solid wedges to show the stereochemistry of the substituent groups. To be graded properly, include the hydrogen atoms on the chirality centers (asymmetric carbons).
Determine the root-mean-square speed of CO2 molecules that have an average kinetic energy of 4.2 x 10^-21 J per molecule.
A sample of solid having a density of 3.43 g/cm3 had an apparent mass of 13.9264. The density of the balance weights is 8.00 g/cm3. Calculate the true mass of the object.
If the pH probe was miscalibrated and reports the pH and reports the pH to be 1 unit higher than the true pH of the solution it is in, would the molar mass you report for the solid acid be higher than
liquid hexane will react with gaseous oxygen to produce gaseous carbon dioxide and gaseous water . suppose 7.8 g of
write a balance chemical equation for the combustion of 1 mol glycerin, and calculate delta H for this reaction at 298K if burning 1 mol glycerin has a delta E of -54.6 kj
what is the condensed structural formula of 4-isopropylheptane?
What is the bond order of a molecule with 10 valence electrons 12valence electrons,13 valece electrons,14 valence electrons
The diatomic molecule AB has a dipole moment of 1.21 D and the A-B bond distance is 115 pm. Determine the percent ionic character of the bond in AB
By mistake, a worker at an electroplating shop mixes a small amount of sulfuric acid into a large tank of wastewater containing sodium cyanide. The reaction produces a toxic gas, hydrogen cyanide, as shown below:
(a) Calculate the percent ionization of 0.00190 M acetic acid (Ka = 1.8e-05). % ionization = % (b) Calculate the percent ionization of 0.00190 M acetic acid in a solution containing 0.0710 M sodium acetate. % ionization = %
Calculate the number of moles of magnesium, chlorine, and oxygen atoms in 8.30 moles of magnesium perchlorate Mg(ClO4)2
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