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Bromination of Toluene
If you treat toluene with 2 equivalences of bromine, you will get aminly 2,4-dibromotoluene and not 2, 6-dibromotoluene. However, you can produce 3, 5-dibromotoluene by treating 4-aminotoluene with 2 equivalences of bromine. Then first treating the product, 4-amino-3,5-dibromotoluene, with HNO2 in H2SO4, and secondly treating the resulting product with hypophosphorus acid, H3PO2. Fully explain why this series of reaction will produce the 3,5-dibromotoluene and direct bromination of toluene produces the 2,4-dibromotoluene.
The half-life of Plutonium-239 is 24,000 years. If 10 gms are present now, how long will it take until only 10% of the original sample remains? Round your answer to the nearest 10,000th.
Determine how many moles of SO 3 are formed if 12.24 moles of O 2 react with excess SO 2 ,? use the balance equation given as 2SO 2 (g)+O 2 (g)----> 2SO 3 (g)
A 50.0g silver object and a 45.0 g gold object are both added to a 55.5 mL of water contained in a graduate cylinder. what is the new water level in the cylinder.
When making an alcoholic beverage, such as beer and wine, Brix is a measurement used to assess the amount of sugar present in the fermentation matrix or grape juice.
Questions on H-NMR spectrum of isopentyl acetate - What would the effect on yield be of allowing the crushed Dry Ice to be exposed to the atmosphere for long periods of time before being used?
determine the heat released when (ethene) CH2 CH2 reacts with hydrogen gas and form CH3CH3.If Bond enthalpies given are H H : 436 kJ/mol,C Br : 276 kJ/mol,C C : 612 kJ/mol,C C : 348 kJ/mol,C H : 412 kJ/mol;
A buffer is made using 45.0 mL of 0.750 M HC3H5O2 and 55.0 mL of 0.700 M NaC3H5O2.What volume of 0.10 M NaOH must be added to change the pH of the original buffer solution by 2.5%? Ka for this acid is 1.3 x 10
a certain liquid has dH(vap)=26.0kJ/mol. calculate the q,w,dH and dU when 0.50 mol is vaporized at 250K and 750torr
3H2 + N2 -> 2NH3. At 200 degrees C in a closed container, 1.00atm of nitrogen gas is mixed with 2.00atm of hydrogen gas. At equilibrium, the total partial pressure is 2.00atm.
A piston has an external pressure of 11.0 bar . How much work has been done if the cylinder goes from a volume of 0.150 liters to 0.570 liters.
A 29.0-g sample of water at 260. K is mixed with 48.0 g water at 300. K. Calculate the final temperature of the mixture assuming no heat loss to the surroundings.
A cook wants to heat 1.35 of water from 32.0 to 100.0 .If he uses the combustion of natural gas (which is exothermic) to heat the water, how much natural gas will he need to burn.
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