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Introduction to the Nernst Equation Learning Goal: To learn how to use the Nernst equation. The standard reduction potentials listed in any reference table are only valid at standard-state conditions of 25 circ C and 1 M. To calculate the cell potential at non-standard-state conditions, one uses the Nernst equation, E = E^\circ - \frac{2.303\,RT}{ nF}\log Q where E is the potential in volts, E^\circ is the standard potential in volts, R = 8.314 J/(K * mol) is the gas constant, T is the temperature in kelvins, n is the number of moles of electrons transferred, F= 96,500 C (mol ~e^-) is the Faraday constant, and Q is the reaction quotient. Consider the reaction Mg (s)+ Fe^2+(aq) \rightarrow Mg^2+(aq)+ Fe (s) at 83\;^\circ C , where [ Fe^2+]= 3.60 M and [ Mg 2+]= 0.310M . Part A What is the value for the reaction quotient, Q, for the cell?
What minimum amount of AX(s) lattice energy might lead to compound formation if you predict that the following hypothetical ionic compound AX is unlikely to form. In this compound, A forms the A+ cation, and X forms the X anion.
Explain why a 1m solution of the compound FeCl2 in water has a lower freezing temperature than a 1m solution of KCl in water and what is the empirical formula of a compound
If the final temperature of the combined liquids is 28.5°C and the heat capacity of the calorimeter is 19.3 J/°C, determine the specific heat of methanol.
A piston at 7.4 atm contains a gas that occupies a volume of 3.5 L. What pressure would have to be placed on the piston to force the volume to adjust to 1.27 L
Suggest mathematical functions that represent a sinusoidal wave of amplitude A, frequency v, and wavelength
Concentrated sulfuric acid is used as a catalyst for the esterfication of acetic acid in the preparation of isopentyl acetate. Why is the sulfuric acid needed if another acid,
25 mL of 0.10 M HCl is mixed with 25 mL of .43 M NH3. What is the resulting pH?
Given the initial concentrations of 0.10 atm NO2 and 0.10 atm N2O4 in a 1.0 L flask, what will be the equilibrium partial pressure of NO2? N2O4(g) ? 2 NO2(g) Kp = 0.660 at 319 K
What is the standard change in Gibbs free energy of this reaction at 25 °C. Hint: The equilibrium constant is related to the change in Gibbs free energy
At the equivalence point all carbonate has been converted to bicarbonate NEt ionic equation before the equivalence point: Net ionic equation at the equivalence point
What is methanol's vapor pressure It boils at 65.0 °C and has a heat of vaporization ΔHvap = 37.4 kJ/mol. at 22.0 °C?
how many moles O2 of are present? (The mole fraction of in dry air is 0.2095.) How many grams of C8H18 could be combusted by this quantity of O2
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