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Consider a reversible heat engine operating between two reservoirs, R1 and R2, initially at temperatures TH and TC, respectively, where TH > TC. Assume that the cold reservoir, R2, has an infinite heat capacity (i.e. TC = constant) but that the hot reservoir, R1, is finite with a constant heat capacity C1. Accordingly the temperature of R1 decreases with time from its initial value of TH. In each cycle, the heat engine absorbs an infinitesimal amount of heat dq from R1, converts part of it into work dw, and rejects the remaining heat into R2. The engine stops working when the temperature of the hot reservoir has been lowered to TC. Show that the amount of work done by the engine is W = C1(TH-TC) - C1TC ln (TH/TC).
If 2 atoms of silver metal react with 1 molecule of fluorine gas at constant pressure, 2 formula units of solid sodium fluoride are produced and 409.2 kJ of heat is released.
Calculate the pH of a buffer formed by mixing 85 ml of 0.12 M lactic acid with 95 ml of 0.15 M sodium lactate.
Calculate the pH of a buffer solution that is 0.250 M in HCN and 0.170 M in KCN. For HCN, Ka = 4.9 x 10^-10 (pka = 9.31). Use the equilibirum approach to calculate
What is the millimolar (mM) concentration of ethanol in the blood at this limit. The density of ethanol is 0.789 g/ml.
Draw the structural formula(s) for the branched constitutional isomer(s) with the molecular formula C7H16 that do not have a methyl
pure nitrogen can be prepared when an aqueous solution of ammonium nitrite decomposes to form water vapor and nitrogen
Explain the naming laws to name elements. and also how to derive the chemical formula from the names given.
A 13.386 g aliquot of this solution is then titrated with 0.1052 M HCl. It required 30.21 mL of the HCl solution to reach the methyl red endpoint. Calculate the weight percent NH3 in the aqueous waste.
To reduce pollution when coal is burned, it is important to remove mercury and sulfur compounds from the effluent. Identify which, ifany, ofthe following redox reactions are spontaneous under standard conditions and therefore might be used for thi..
The nitrate concentration in an industrial effluent is determined using a nitrate ion selective electrode. Standards and samples are diluted 20-fold with 0.100 K2SO4 to maintain consatnt ionic strength.
Calculate the amount of PV work done. c2h4(g)+h2(g)-->c2h6(g) Express your answer using two significant figures. The addition of H2 to C=C double bonds is an important reaction used in the preparation of margarine from vegetable oils.
How many centimeters does light travel in 5.00 years (given that the velocity of light is 3.00 \times 10^{10} {\rm cm}/{\rm s})? Express your answer with the appropriate units.
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