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A 0.150 M aqueous solution of the weak inorganic acid HA was prepared from the pure compound, and three 50.0 mL aliquots were transferred to 100.0 mL volumetric flasks. Solution 1 was diluted to 100.0 mL with 1.0 M HClO4; solution 2 with 1.0 M NaOH, solution 3 with water. A 25.0 mL aliquot of each was extracted with 25.0 mL of n-hexane. The extract from solution 2 contained no detectable trace of A-containing species, indicating that A^- is not soluble in the organic solvent. The extract from solution 1 contained no ClO4- or HClO4 but was found to be 0.0454 M in HA (by extraction with standard NaOH and back-titration with standard HCl). The extract from solution 3 was found to be 0.0225M in HA. Assume that HA does not associate or dissociate in the organic solvent, calculate a.) the distribution ratio for HA between the 2 solvents. b.) the concentration of the species HA and A^- in aqueous solution 3 after extraction c.) The dissociation constant of HA in water.
The activation energy of a certain reaction is 45.3kJ/mol . At 24{~}^{\circ}\rm C , the rate constant is 0.0160s^{-1} . At what temperature in degrees Celsius would this reaction go twice as fast?
Determine how many grams of NaCl should be dissolved in a liter of H 2 O to produce an isotonic solution?
63mL of a 1.70 M solution is diluted to a volume of 218 mL. A 109mL portion of the solution is diluted using 117mL of water. What is the final concentration?
A graduated cylinder contains 129 mL of water. A 17.0 g piece of iron (density = 7.86 rm{g/cm^3}) and a 17.0 g piece of lead are added. What is the new water level in the cylinder?
55.0 mL of a 1.70 M solution is diluted to a volume of 278 mL. A 139 mL portion of that solution is diluted using 175 mL of water. What is the final concentration.
How many hours will it take to produce 61.0 kg of Al metal by the reduction of Al3+ in an electrolytic cell using a current of 484 amps?
An aliquot of 14.045 grams of this solution is titrated with 0.1043 M hydrochloric acid (HCl.) and it required hydrochloric acid (HCl solution) of 29.18 mL to reach the methyl red endpoint. Compute the weight % Ammonia (NH3) in the aqueous waste.
If ΔH = -60.0kJ and ΔS = -0.200kJ/K , the reaction is spontaneous below a certain temperature. Calculate that temperature. Express your answer numerically in kelvins.
A student measures the standard enthalpy change for reaction (C2H4(g) + H2O(g) CH3CH2OH(g)) to be -52.8 kJ :Calculate the standard enthalpy of formation.
determine the final volume of the gas If the gas ocupied 68mL, initally and determine the molarity of the solution
The half-life of carbon-14 is 5,730 years. If you started with 100.0 g of carbon-14, how much carbon-14 would remain after 4 half-lives.
calculate the solubility of potassium bromide at 23 degrees celuius.assume that the solubility increases by an equal amount for each degree between 20 and30 degrees
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