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Suppose life has been discovered on another planet in a distant solar system. Organelles corresponding to our mitochondria transform energy by a Mitchell-like chemiosmotic mechanism. The flow of electrons drives the production of a pH gradient in the same direction. The only difference is the H+-ATP stoichiometry. •• Given that the pH on the outside of the xeno-mitochondrial membrane is 6.014, the pH on the inside is 7.568, ?G for ATP synthesis is 12.85 kcal/mol, and the alien body temperature is 27.3oC, calculate how many protons are required to pass through the xeno-FoF1-ATP synthase complex to synthesize one ATP. Round off your answer to the nearest integral value. (Assume, as we have done in class, that sufficient "power" to synthesize ATP exists when ?G for transporting protons across the membrane equals ?G for ATP synthesis.)
Ammonium carbamate (NH2COONH4) is found in the blood and urine of mammals. At a temperature of 466 K, Kc = 0.080 for the following equilibrium: NH2COONH4(s) 2 NH3(g) + CO2(g). If 10.2 g of ammonium carbamate is introduced into a 0.500 L containe..
The well-preserved remains of a now extinct woolly mammoth is entombed in the permafrost lands of Siberia. Scientists have conducted carbon dating experiments on plant debris found in the stomachs of this mammoth.
Compute the number of moles of sodium hydroxide ( NaOH ) in 23.75cm 3 of 0.150moldm -3
Silver chloride crystallizes with the sodium chloride (rock salt) structure. The length of a unit cell edge is 555 pm. What is the density of AgCl? Show all works.
is it possible to determine the amount of impurity formed in aspirin with excess sodium salt. aspirin had a melting point range of 113-135 degrees celsius. that is all the information given. any other info can be used.
Compute the cell potential(E) after the reaction has operated long enough for the [Al3+] to have changed by .60 mol/L. suppose T=25 C
The air in an inflated balloon (defined as the system) is warmed over a toaster and absorbs 115 J of heat. As it expands, it does 77 kJ of work. what is it change in internal energy for the system?
As of 2007 world record for swimming 1500.0 m in a long course pool is 14 min 34.56 s. if we follow this rate then calculate how many seconds would be taken by a man to swim 0.850 miles?
A 80.0-L stainless steel container was charged with 4.00 atm of hydrogen gas and 5.00 atm of oxygen gas. A spark ignited the mixture, producing water. What is the pressure in the tank at a constant temperature of 25°C?
What effect does the presence of lone-pair electrons have on the bond angles and the geometry of a molecule?
Calculate the pH at the equivalence point for titrating 0.250 solutions of each of the following bases with 0.250 M HBr
Consider the cell described below. Al | Al3+ (1.00 M) || Pb2+ (1.00 M) | Pb Calculate the cell potential after the reaction has operated long enough for the [Al3+] to have changed by 0.32 mol/L. (Assume T = 25°C.)
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