Define kinetics of double-stranded formation for a dodecamer

Reference no: EM13336641

The kinetics of double-stranded formation for a dodecamer containing two G.T base pairs was measured by temperature-jump kinetics. The reaction is: 2 CGTGAATTCGCG <--> DUPLEX The following data were obtained: T oC k1 (105 M-1 s-1) k-1 (s-1) 31.8 0.8 1.00 36.8 2.3 3.20 41.8 3.5 15.4 46.7 6.0 87.0 A.Determine Delta_H* and Delta_S* for the forward and reverse processes. Assume that the values of Ea, Delta_H* and Delta_S* are independent of temperature. You assume that Delta_H* = Ea. Delta_H* (forward) =

Reference no: EM13336641

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